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Active material, nonaqueous electrolyte battery, battery pack and battery module

專利號(hào)
US10096827B2
公開日期
2018-10-09
申請(qǐng)人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuhiro Harada; Norio Takami; Yorikazu Yoshida; Kazuki Ise
IPC分類
H01M4/00; H01M4/485; C01G23/00; H01M4/131; H01M4/36; H01M10/052; C01G25/00; C01G31/00; C01G33/00; C01G35/00; C01G39/00; C01G49/00; C01G51/00; H01M4/62; H01M10/0525; H01M4/02
技術(shù)領(lǐng)域
electrode,fmmm,battery,nonaqueous,composite,oxide,in,example,li2co3,lithium
地域: Minato-ku

摘要

In general, according to one embodiment, there is provided an active material. The active material contains a composite oxide having an orthorhombic crystal structure. The composite oxide is represented by a general formula of Li2+wNa2?xM1yTi6?zM2zO14+δ. In the general formula, the M1 is at least one selected from the group consisting of Cs and K; the M2 is at least one selected from the group consisting of Zr, Sn, V, Nb, Ta, Mo, W, Fe, Co, Mn, and Al; and w is within a range of 0≤w≤4, x is within a range of 0

說明書

First, particles of the product of Example A-5 were ground so that the average particle size was 5 μm or less to obtain a ground product. Next, acetylene black, as a conductive agent, was mixed with the active material in an amount of 6 parts by mass relative to the active material to obtain a mixture. Next, the mixture was dispersed in NMP (N-methyl-2-pyrrolidone) to obtain a dispersion. Polyvinylidene fluoride (PVdF), as a binder, was mixed with the dispersion in an amount of 10 parts by mass relative to the product of Example A-5 to prepare a negative electrode slurry. A current collector, formed of aluminum foil, was coated with the slurry using a blade. After the obtained product was dried at 130° C. for 12 hours in vacuum, it was rolled so that a density of the electrode layer (excluding a current collector) was 2.2 g/cm3 to obtain a negative electrode.

(Production of Positive Electrode)

With a commercially available spinel lithium manganese oxide (LiMn2O4) was mixed 5 parts by weight of acetylene black as a conduction aid to obtain a mixture. Next, the mixture was dispersed in NMP to obtain a dispersion. To the dispersion was mixed with PVdF, as a binder, in an amount of 5 parts by weight relative to the lithium manganese oxide to prepare a positive electrode slurry. A current collector, formed of an aluminum foil, was coated with the slurry using a blade. After the obtained product was dried at 130° C. for 12 hours in vacuum, it was rolled so that a density of the electrode layer (excluding a current collector) was 2.1 g/cm3, to obtain a positive electrode.

(Production of Electrode Group)

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