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Active material, nonaqueous electrolyte battery, battery pack and battery module

專利號
US10096827B2
公開日期
2018-10-09
申請人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuhiro Harada; Norio Takami; Yorikazu Yoshida; Kazuki Ise
IPC分類
H01M4/00; H01M4/485; C01G23/00; H01M4/131; H01M4/36; H01M10/052; C01G25/00; C01G31/00; C01G33/00; C01G35/00; C01G39/00; C01G49/00; C01G51/00; H01M4/62; H01M10/0525; H01M4/02
技術(shù)領(lǐng)域
electrode,fmmm,battery,nonaqueous,composite,oxide,in,example,li2co3,lithium
地域: Minato-ku

摘要

In general, according to one embodiment, there is provided an active material. The active material contains a composite oxide having an orthorhombic crystal structure. The composite oxide is represented by a general formula of Li2+wNa2?xM1yTi6?zM2zO14+δ. In the general formula, the M1 is at least one selected from the group consisting of Cs and K; the M2 is at least one selected from the group consisting of Zr, Sn, V, Nb, Ta, Mo, W, Fe, Co, Mn, and Al; and w is within a range of 0≤w≤4, x is within a range of 0

說明書

The subscript x in the general formula of Li2+wNa2?xM1yTi6?zM2zO14+δ for the composite oxide indicates an Na amount in the crystal structure in this composite oxide. The active material for a battery according to the first embodiment can control an average operating potential of an electrode containing the active material for a battery within a range of 1.2 V (vs. Li/Li+) to 1.5 V (vs. Li/Li+) to the oxidation-reduction potential of the metal lithium by changing the Na amount in the crystal structure, i.e., the value of the subscript x, whereby the operating potential of the battery can be easily designed. From a different aspect, the subscript x is an index showing a ratio of a part which is substituted by the cation M1 or the vacancy in the substituted composite oxide, among the sites corresponding to the Na sites in the composite oxide Li2+wNa2Ti6O14+δ. The subscript x is within a range of 0<x<2, preferably 0.1≤x≤0.9, more preferably 0.25≤x≤0.75.

權(quán)利要求

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