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Active material, nonaqueous electrolyte battery, battery pack and battery module

專利號
US10096827B2
公開日期
2018-10-09
申請人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuhiro Harada; Norio Takami; Yorikazu Yoshida; Kazuki Ise
IPC分類
H01M4/00; H01M4/485; C01G23/00; H01M4/131; H01M4/36; H01M10/052; C01G25/00; C01G31/00; C01G33/00; C01G35/00; C01G39/00; C01G49/00; C01G51/00; H01M4/62; H01M10/0525; H01M4/02
技術(shù)領(lǐng)域
electrode,fmmm,battery,nonaqueous,composite,oxide,in,example,li2co3,lithium
地域: Minato-ku

摘要

In general, according to one embodiment, there is provided an active material. The active material contains a composite oxide having an orthorhombic crystal structure. The composite oxide is represented by a general formula of Li2+wNa2?xM1yTi6?zM2zO14+δ. In the general formula, the M1 is at least one selected from the group consisting of Cs and K; the M2 is at least one selected from the group consisting of Zr, Sn, V, Nb, Ta, Mo, W, Fe, Co, Mn, and Al; and w is within a range of 0≤w≤4, x is within a range of 0

說明書

In an X-ray diffraction diagram for the composite oxide represented by the general formula of Li2+wNa2?xM1yTi6?zM2zO14+δ, obtained by a powder X-ray diffraction using Cu—Kα rays, it is preferable that an intensity ratio IL/IH is within a range of 2.25≤IL/IH≤3.50, wherein IL is an intensity of a strongest diffraction peak appearing in a range of 17°≤2θ≤18.5°, and IH is an intensity of a strongest diffraction peak appearing in a range of 18.5°<2θ≤19.5°.

A composite oxide according to another example of the preferable aspects in which the intensity ratio IL/IH is within a range of 2.25≤IL/IH≤3.5 in an X-ray diffraction diagram of a composite oxide, obtained according to a powder X-ray diffraction, is a composite oxide having an orthorhombic crystal structure belonging to a space group Fmmm. In such a composite oxide, in the X-ray diffraction diagram of the composite oxide obtained by the powder X-ray diffraction using Cu—Kα rays, an intensity ratio is within a range of 2.25≤IL1/IH1≤3.5, wherein IL1 is an intensity of a diffraction peak corresponding to a (111) plane, and IH1 is an intensity of a diffraction peak corresponding to a (202) plane.

FIG. 2 is a crystal structure view of Li2Na1.5Ti5.5Nb0.5O14 which is one example of the composite oxide having the symmetry of the space group Fmmm.

In the crystal structure shown in FIG. 2, the smallest spheres 100 indicate positions of oxide ions.

權(quán)利要求

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