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Active material, nonaqueous electrolyte battery, battery pack and battery module

專利號
US10096827B2
公開日期
2018-10-09
申請人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuhiro Harada; Norio Takami; Yorikazu Yoshida; Kazuki Ise
IPC分類
H01M4/00; H01M4/485; C01G23/00; H01M4/131; H01M4/36; H01M10/052; C01G25/00; C01G31/00; C01G33/00; C01G35/00; C01G39/00; C01G49/00; C01G51/00; H01M4/62; H01M10/0525; H01M4/02
技術領域
electrode,fmmm,battery,nonaqueous,composite,oxide,in,example,li2co3,lithium
地域: Minato-ku

摘要

In general, according to one embodiment, there is provided an active material. The active material contains a composite oxide having an orthorhombic crystal structure. The composite oxide is represented by a general formula of Li2+wNa2?xM1yTi6?zM2zO14+δ. In the general formula, the M1 is at least one selected from the group consisting of Cs and K; the M2 is at least one selected from the group consisting of Zr, Sn, V, Nb, Ta, Mo, W, Fe, Co, Mn, and Al; and w is within a range of 0≤w≤4, x is within a range of 0

說明書

On the other hand, in order to determine the previously described intensities IL and IH (IL1 and IH1) of diffraction peaks for the composite oxide, the powder X-ray diffraction results measured under the above conditions without processing, i.e., raw data is used. The peak top, i.e., the maximum intensity of a strongest diffraction peak appearing within the range of 17°≤2θ≤18.5° is defined as IL. On the other hand, the peak top; i.e., the maximum intensity of a strongest diffraction peak appearing within the range of 18.5°<2θ≤19.5° is defined as IH. An intensity ratio IL/IH can be calculated by dividing the intensity numerical value (counts per second: cps) of the intensity IL by the intensity numerical value (cps) of the intensity IH.

When the active material to be measured is contained in the electrode material of the nonaqueous electrolyte battery, first, the electrode is taken out from the nonaqueous electrolyte battery according to the previously described procedure. The taken-out and washed electrode is cut to the size almost equal to the area of the holder of a powder X-ray diffractometer, and used as the measurement sample.

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