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Active material, nonaqueous electrolyte battery, battery pack and battery module

專利號
US10096827B2
公開日期
2018-10-09
申請人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuhiro Harada; Norio Takami; Yorikazu Yoshida; Kazuki Ise
IPC分類
H01M4/00; H01M4/485; C01G23/00; H01M4/131; H01M4/36; H01M10/052; C01G25/00; C01G31/00; C01G33/00; C01G35/00; C01G39/00; C01G49/00; C01G51/00; H01M4/62; H01M10/0525; H01M4/02
技術(shù)領域
electrode,fmmm,battery,nonaqueous,composite,oxide,in,example,li2co3,lithium
地域: Minato-ku

摘要

In general, according to one embodiment, there is provided an active material. The active material contains a composite oxide having an orthorhombic crystal structure. The composite oxide is represented by a general formula of Li2+wNa2?xM1yTi6?zM2zO14+δ. In the general formula, the M1 is at least one selected from the group consisting of Cs and K; the M2 is at least one selected from the group consisting of Zr, Sn, V, Nb, Ta, Mo, W, Fe, Co, Mn, and Al; and w is within a range of 0≤w≤4, x is within a range of 0

說明書

As apparent from the following Table 3, in Comparative Examples A-1a and A-1b, the obtained results of the intensity ratio IL/IH of the diffraction peaks were different from each other, though the target compositions are the same. In Comparative Example A-1a, the sintering was performed at one time at 1000° C. for a long time without considering the vaporization amount of Li. On the other hand, in Comparative Example A-1b, the synthesis was performed in the same manner as in Example A-1 of the present application. It can be considered therefore that if the sintering condition or the feed amount of the lithium starting materials is different, the crystallite growing condition is also different.

On the other hand, the results of the powder X-ray diffraction were analyzed according to a Rietveld method. As a result, it was found that the products obtained in Examples A-1 to A-14 were orthorhombic type compounds having the space group Fmmm symmetry shown in FIG. 2. Crystal phases and space groups of the products are shown in Table 3 altogether.

權(quán)利要求

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