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Method for producing a silver sintering agent having silver oxide surfaces and use of said agent in methods for joining components by pressure sintering

專利號(hào)
US10785877B2
公開日期
2020-09-22
申請(qǐng)人
Heraeus Deutschland GmbH & Co. KG(DE Hanau)
發(fā)明人
Michael Sch?fer; Wolfgang Schmitt
IPC分類
H05K3/32; H01L23/00; B22F7/04; B22F5/00; B22F3/10; B22F3/14; B23K35/02; B23K35/30; C23C8/10; C25D11/34; H05K1/09
技術(shù)領(lǐng)域
silver,sintering,oxide,oxidizable,layer,agent,in,surfaces,acid,sintered
地域: Hanau

摘要

A method for the production of a silver sintering agent in the form of a layer-shaped silver sintering body having silver oxide surfaces and the use thereof are provided.

說明書

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Exemplary Embodiment and Application Example 1

Stencil printing was used to apply a layer of a silver sintering paste (ASP 043-04P2 from Heraeus Materials Technology) sized 10×10 mm2 onto a support substrate in the form of a polytetrafluoroethylene film at a wet layer thickness of 100 μm, which was then sintered for 30 min in a circulating-air drying cabinet at an object temperature of 250° C.

The sintered product was carefully detached from the support substrate using a suction pipette to obtain a free layer-shaped silver sintering body.

A 10 wt % aqueous sodium carbonate solution was placed in a stainless steel vessel and the stainless steel vessel was connected to the cathode of a 10 V direct voltage source. The anode of the voltage source was connected to the free layer-shaped silver sintering body and the latter was then immersed in the sodium carbonate solution for 30 seconds.

Once it was taken out, the blackened surface of the free layer-shaped silver sintering body resulting from anodic oxidation was rinsed with deionized water and then dried. Subsequently, one droplet of a 2 wt. % lauric acid solution in Exxsol D60 was placed on the silver oxide surfaces on the front and rear side, distributed evenly, and dried in a circulating-air heating cabinet at 70° C. Then the silver sintering body thus provided with lauric acid was joined between the gold surface of a corresponding DCB substrate and the silver contact surface of an IGBT sized 10×10 mm2 and the sandwich arrangement thus produced was sintered in a sintering press for 120 seconds at an object temperature of 250° C. and a mechanical pressure of 20 MPa.

權(quán)利要求

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