Purification was performed by gradually increasing the proportion of toluene to hexane from 1:1 in a developing solvent. The obtained filtrate was concentrated, whereby 1.1 g of a target yellow solid of 8-chloro-4-(9′-phenyl-2,3′-bi-9H-carbazol-9-yl)benzofuro[3,2-d]pyrimidine was obtained with a yield of 45%. The synthesis scheme of Step 1 is shown in (A-1) below.