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Membrane-electrode assembly for fuel cell, method for manufacturing same, and fuel cell system comprising same

專利號
US10868311B2
公開日期
2020-12-15
申請人
KOLON INDUSTRIES, INC.(KR Gwacheon-si)
發(fā)明人
Dong Jun Cho
IPC分類
H01M4/88; H01M8/04298; H01M4/92; H01M8/1018; H01M4/86; H01M8/1004; H01M8/1007; H01M8/0239
技術(shù)領(lǐng)域
catalyst,porous,electrode,membrane,fuel,binder,support,nanoweb,layer,resin
地域: Gwacheon-si

摘要

Disclosed are a membrane-electrode assembly for fuel cells, a method of manufacturing the same and a fuel cell system containing the same. The membrane-electrode assembly for fuel cells includes an anode and a cathode facing each other, and a polymer electrolyte membrane interposed between the anode and the cathode, wherein at least one of the anode and the cathode further includes a porous support and a catalyst layer for fuel cells disposed on one surface of the porous support. The electrode of the membrane-electrode assembly is a free-standing electrode, and the electrode has excellent adhesivity to the polymer electrolyte membrane and thus can prevent performance deterioration resulting from detachment of the electrode from the polymer electrolyte membrane during operation of fuel cells, and in particular, can secure high durability since the electrode is not readily detached even under harsh operation environments.

說明書

The electrode for fuel cells 10 includes the second region 14 composed of only the binder resin, the first region 13 composed of the binder resin and the catalyst, and the binder resin and the catalyst, so that the interface between the binder resin and the catalyst can be created in the form of a layer.

Meanwhile, the electrode for fuel cells 10 may further include an electrode substrate (not shown), if necessary. The electrode substrate functions to support the electrode 10 and to enable a fuel and an oxidizing agent to easily access the catalyst layer 12 by diffusing the fuel and the oxidizing agent into the catalyst layer 12.

The electrode substrate may be carbon paper, carbon cloth, carbon felt, carbon fiber or a combination thereof and preferably is carbon fiber.

The electrode substrate may include pores. In this regard, by controlling the size and porosity of the pores, functions of the fuel cell can be improved. Specifically, the electrode substrate may include mean pores with a diameter of 20 to 40 μm at a porosity of 30 to 80 vol % with respect to the total volume of the electrode substrate. Specifically, the electrode substrate may include mean pores with a diameter of 20 to 30 μm at a porosity of 50 to 80 vol % with respect to the total volume of the electrode substrate.

In addition, if necessary, the electrode for fuel cells 10 may further include a microporous layer (not shown) in order to improve diffusion of reactants.

The microporous layer may have a thickness of 3 to 80 μm, specifically a thickness of 10 to 70 μm.

權(quán)利要求

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