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System and method for preparing vanadium battery high-purity electrolyte

專(zhuān)利號(hào)
US10868325B2
公開(kāi)日期
2020-12-15
申請(qǐng)人
INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCES; BEIJING ZHONGKAIHONGDE TECHNOLOGY CO., LTD(CN Beijing CN Beijing)
發(fā)明人
Haitao Yang; Qingshan Zhu; Chuanlin Fan; Wenheng Mu; Jibin Liu; Cunhu Wang; Qixun Ban
IPC分類(lèi)
H01M8/18; H01M10/0562; B01J8/00; B01J8/18; B01J19/00; B01J19/24; C01G31/02; B01J14/00
技術(shù)領(lǐng)域
vanadium,cyclone,gas,pipeline,pentoxide,preheater,inlet,valence,outlet,feed
地域: Beijing

摘要

A system and method for preparing a vanadium battery high-purity electrolyte, comprising preparing a low-valence vanadium oxide with a valence of 3.5 with liquid phase hydrolysis and fluidization reduction with vanadium oxytrichloride, adding clean water and sulfuric acid for dissolution, and further performing ultraviolet activation to obtain the vanadium electrolyte, for use in an all-vanadium redox flow battery stack. The high-temperature tail gas in the reduction fluidized bed is combusted for preheating the vanadium powder material, to recover the sensible heat and latent heat of the high-temperature tail gas, and the sensible heat of the reduction product is recovered through heat transfer between the reduction product and the fluidized nitrogen gas. An internal member is arranged in the reduction fluidized bed to realize the precise regulation of the valence state of the reduction product, and ultraviolet is used to activate the vanadium ions, improving the activity of the electrolyte.

說(shuō)明書(shū)

a clean water inlet of the dissolution reactor 10 is connected with the clean water main pipe through a pipeline; a concentrated sulfuric acid inlet of the dissolution reactor 10 is connected with a concentrated sulfuric acid main pipe through a pipeline; a gas outlet of the dissolution reactor 10 is connected with the tail gas treatment system; and a primary electrolyte outlet of the dissolution reactor 10 is connected with a primary electrolyte inlet of the activation device 11 through a pipeline.

The present invention further provides a method for preparing a vanadium battery high-purity electrolyte based on the above system, which comprises the following steps:

allowing vanadium oxytrichloride liquid in the vanadium oxytrichloride storage tank 1 to enter the liquid phase hydrolysis reaction tank 2-1 through a pipeline, and then be subjected to hydrolysis precipitation together with clean water from the clean water main pipe to form a mixed slurry of vanadium pentoxide precipitate and hydrochloric acid solution; transmitting the produced acid gas to the tail gas treatment system through a pipeline; allowing the slurry to enter the washing filter 2-2 and be subjected to washing with clean water and filtration to obtain washing liquid and vanadium pentoxide precipitate powder; transmitting the washing liquid to the wastewater treatment system; and transmitting the vanadium pentoxide precipitate to the vanadium pentoxide hopper 3-1;

權(quán)利要求

1
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