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System and method for preparing vanadium battery high-purity electrolyte

專利號
US10868325B2
公開日期
2020-12-15
申請人
INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCES; BEIJING ZHONGKAIHONGDE TECHNOLOGY CO., LTD(CN Beijing CN Beijing)
發(fā)明人
Haitao Yang; Qingshan Zhu; Chuanlin Fan; Wenheng Mu; Jibin Liu; Cunhu Wang; Qixun Ban
IPC分類
H01M8/18; H01M10/0562; B01J8/00; B01J8/18; B01J19/00; B01J19/24; C01G31/02; B01J14/00
技術(shù)領(lǐng)域
vanadium,cyclone,gas,pipeline,pentoxide,preheater,inlet,valence,outlet,feed
地域: Beijing

摘要

A system and method for preparing a vanadium battery high-purity electrolyte, comprising preparing a low-valence vanadium oxide with a valence of 3.5 with liquid phase hydrolysis and fluidization reduction with vanadium oxytrichloride, adding clean water and sulfuric acid for dissolution, and further performing ultraviolet activation to obtain the vanadium electrolyte, for use in an all-vanadium redox flow battery stack. The high-temperature tail gas in the reduction fluidized bed is combusted for preheating the vanadium powder material, to recover the sensible heat and latent heat of the high-temperature tail gas, and the sensible heat of the reduction product is recovered through heat transfer between the reduction product and the fluidized nitrogen gas. An internal member is arranged in the reduction fluidized bed to realize the precise regulation of the valence state of the reduction product, and ultraviolet is used to activate the vanadium ions, improving the activity of the electrolyte.

說明書

An aeration air inlet of the feeder 5-1 is connected with a purified nitrogen gas main pipe; a feed outlet of the feeder 5-1 is connected with a feed inlet of the bed body 5-2 through a pipeline; a gas inlet of the bed body 5-2 is connected with a gas outlet of the gas heater 5-4 through a pipeline; a gas inlet of the gas heater is connected with a gas outlet of the second cyclone separator 7-3 and a gas outlet of the gas purifier 5-5 through pipelines; a combustion air inlet of the gas heater 5-4 is connected with a compressed air main pipe; a fuel inlet of the gas heater 5-4 is connected with a fuel main pipe; a gas inlet of the gas purifier 5-5 is connected with a reducing gas main pipe; a feed outlet of the bed body 5-2 is connected with a feed inlet of the discharger 5-3 through a pipeline; an aeration air inlet of the discharger 5-3 is connected with the purified nitrogen gas main pipe; a feed outlet of the discharger 5-3 is connected with a feed inlet of the venturi cooler 7-1 through a pipeline; a gas outlet of the bed body 5-2 is connected with a gas inlet of the first cyclone separator 5-6 through a pipeline; a feed outlet of the first cyclone separator 5-6 is connected with the feed inlet of the discharger 5-3 through a pipeline; and a gas outlet of the first cyclone separator 5-6 is connected with a gas inlet of the combustion chamber 6 through a pipeline.

A combustion air inlet of the combustion chamber 6 is connected with the compressed air main pipe; and the gas outlet of the combustion chamber 6 is connected with the gas inlet of the venturi preheater through a pipeline.

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