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Secondary battery, battery pack, vehicle, and stationary power supply

專利號
US10868331B2
公開日期
2020-12-15
申請人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuyuki Hotta; Shinsuke Matsuno; Norio Takami
IPC分類
H01M4/02; H01M10/0565; B60L58/10; H01M2/16; H01M10/0525; H01M10/0585; H01M10/42
技術領域
electrode,separator,battery,negative,solid,positive,in,layer,material,secondary
地域: Minato-ku

摘要

According to one embodiment, a secondary battery is provided. The separator includes a porous self-supporting film, a solid electrolyte layer, and a first binder. The solid electrolyte layer is provided on one main surface of the porous self-supporting film. The porous self-supported film and the solid electrolyte layer are adhered with the first binder. The first binder exists on both of the one main surface and another main surface of the porous self-supporting film. The solid electrolyte layer includes solid electrolyte particles and a second binder. The solid electrolyte particles have alkali metal ions conductivity. The polymeric material of the second bonder is a same as the polymeric material of the first material.

說明書

The conductive agent is mixed as needed to raise current collection performance and suppress the contact resistance between the active material and the current collector. Examples of the conductive agent include carbonaceous materials such as acetylene black, Ketjen black, graphite, and coke. The conductive agent may be of one type, or two or more types may be used in mixture.

As the binder, for example, polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVdF), fluorine-based rubber, ethylene-butadiene rubber, polypropylene (PP), polyethylene (PE), carboxymethylcellulose (CMC), polyimide (PI), polyacrylimide (PAI), or the like can be used. The binder may be of one type, or two or more types may be used in mixture.

The mixing ratios of the positive electrode active material, the conductive agent, and the binder in the positive electrode active material-containing layer are preferably 70 mass % to 95 mass %, 3 mass % to 20 mass %, and 2 mass % to 10 mass %, respectively. If the mixing ratio of the conductive agent is 3 mass % or more, the conductivity of the positive electrode can be improved. If the mixing ratio of the conductive agent is 20 mass % or less, decomposition of the aqueous electrolyte on the conductive agent surface can be reduced. If the mixing ratio of the binder is 2 mass % or more, a sufficient electrode strength can be obtained. If the mixing ratio of the binder is 10 mass % or less, the insulating portion of the electrode can be decreased.

權利要求

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