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Secondary battery, battery pack, vehicle, and stationary power supply

專利號(hào)
US10868331B2
公開日期
2020-12-15
申請(qǐng)人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuyuki Hotta; Shinsuke Matsuno; Norio Takami
IPC分類
H01M4/02; H01M10/0565; B60L58/10; H01M2/16; H01M10/0525; H01M10/0585; H01M10/42
技術(shù)領(lǐng)域
electrode,separator,battery,negative,solid,positive,in,layer,material,secondary
地域: Minato-ku

摘要

According to one embodiment, a secondary battery is provided. The separator includes a porous self-supporting film, a solid electrolyte layer, and a first binder. The solid electrolyte layer is provided on one main surface of the porous self-supporting film. The porous self-supported film and the solid electrolyte layer are adhered with the first binder. The first binder exists on both of the one main surface and another main surface of the porous self-supporting film. The solid electrolyte layer includes solid electrolyte particles and a second binder. The solid electrolyte particles have alkali metal ions conductivity. The polymeric material of the second bonder is a same as the polymeric material of the first material.

說明書

A separator was formed by a method similar to the method described in Example 1 except that LiTFSI was omitted. The thickness of the solid electrolyte layer in this separator was about 20 μm. As a result of TG analysis of the solid electrolyte layer, the ratio of the LATP particles in the solid electrolyte layer was 91.0 mass %, and the ratio of the polyvinyl formal resin was 9.0 mass %. The separator will be referred to as a separator SP3 hereinafter.

A secondary battery was obtained by the method similar to the method described in Example 1 except that the separator SP3 was used in place of the separator SP1.

Example 4

A separator was formed by a method similar to the method described in Example 1 except that LLZ(Li7La3Zr2O12) particles were used in place of the LATP particles. The average particle size of the LLZ particles was 1.5 μm. The separator will be referred to as a separator SP4 hereinafter.

A secondary battery was obtained by a method similar to the method described in Example 1 except that the separator SP4 was used in place of the separator SP1.

Example 5

A separator was formed by a method similar to the method described in Example 1 except that the solid content concentration in a solution mixture was changed from 40 mass % to 20 mass %. The thickness of the solid electrolyte layer in this separator was about 19 μm. As a result of TG analysis of the solid electrolyte layer, the ratio of the LATP particles in the solid electrolyte layer was 95.5 mass %, the ratio of the polyvinyl formal resin was 4.1 mass %, and the ratio of the LiTFSI was 0.4 mass %. The separator will be referred to as a separator SP5 hereinafter.

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