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Secondary battery, battery pack, vehicle, and stationary power supply

專利號
US10868331B2
公開日期
2020-12-15
申請人
KABUSHIKI KAISHA TOSHIBA(JP Minato-ku)
發(fā)明人
Yasuyuki Hotta; Shinsuke Matsuno; Norio Takami
IPC分類
H01M4/02; H01M10/0565; B60L58/10; H01M2/16; H01M10/0525; H01M10/0585; H01M10/42
技術(shù)領(lǐng)域
electrode,separator,battery,negative,solid,positive,in,layer,material,secondary
地域: Minato-ku

摘要

According to one embodiment, a secondary battery is provided. The separator includes a porous self-supporting film, a solid electrolyte layer, and a first binder. The solid electrolyte layer is provided on one main surface of the porous self-supporting film. The porous self-supported film and the solid electrolyte layer are adhered with the first binder. The first binder exists on both of the one main surface and another main surface of the porous self-supporting film. The solid electrolyte layer includes solid electrolyte particles and a second binder. The solid electrolyte particles have alkali metal ions conductivity. The polymeric material of the second bonder is a same as the polymeric material of the first material.

說明書

A secondary battery was obtained by a method similar to the method described in Example 1 except that a sodium-containing niobium titanium composite oxide LNT(Li2Na1.5Ti5.5Nb0.5O14) was used as a negative electrode active material in place of the lithium titanium oxide (Li4Ti5O12). The lithium ion insertion/extraction potential of the sodium niobium titanium composite oxide was 1.0 V (vs. Li/Li+) to 1.3 V (vs. Li/Li+).

Comparative Example 4

First, a polyvinylidene fluoride resin having a weight-average molecular weight of 170,000 was dissolved in an organic solvent to prepare a solution. Next, the solution was applied on one surface of a cellulose nonwoven fabric, and the resulting coating was dried to form a PVdF resin film. Next, a separator was formed by a method similar to the method described in Comparative Example 3 except that a cellulose nonwoven fabric having the PVdF resin film formed thereon was used in place of the cellulose nonwoven fabric, and the cellulose nonwoven fabric and a solid electrolyte film were stacked such that the PVdF resin film and the solid electrolyte film were in contact with each other. The separator will be referred to as a separator SP11 hereinafter.

A secondary battery was obtained by a method similar to the method described in Example 1 except that the separator SP11 was used in place of the separator SP1.

<Evaluation Method>

(Microscopic ATR Method)

權(quán)利要求

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