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Electrolyte salts for rechargeable magnesium-ion batteries

專(zhuān)利號(hào)
US10868335B2
公開(kāi)日期
2020-12-15
申請(qǐng)人
UCHICAGO ARGONNE, LLC(US IL Chicago)
發(fā)明人
Ka-Cheong Lau; Chen Liao
IPC分類(lèi)
H01M10/0568; C07F5/02; H01M10/054; H01M10/0569; C07F5/06
技術(shù)領(lǐng)域
mg,magnesium,triglyme,ocr3,in,electrode,ether,ion,salt,thf
地域: IL IL Chicago

摘要

Magnesium salts suitable for use in an electrolyte for a magnesium ion electrochemical cell are described herein. The salts are magnesium tetra(perfluoroalkoxy)metalates, optionally solvated with up to seven ether molecules coordinated to the magnesium ion thereof. In one embodiment, the salt has the empirical formula: Mg(Z)n2+[M(OCR3)4?]2 (Formula (I)) wherein Z is an ether; n is 0 to about 7; M is Al or B; and each R independently is a perfluoroalkyl group (e.g., C1 to C10 perfluoroalkyl). The magnesium salts of Formula (I) are suitable for use as electrolyte salts for magnesium ion batteries (e.g., 5 V class magnesium batteries) and exhibit a wide redox window that is particularly compatible with magnesium anode. The salts are relatively cost effective to prepare by methods described herein, which are conveniently scalable to levels suitable for commercial production.

說(shuō)明書(shū)

One promising approach to an alternative to Li-ion batteries is a battery based on a multivalent ion electrolyte, such as magnesium (Mg) or calcium (Ca). Li-ion, with a charge of +1, can provide only a single electron for an electrical current, whereas multivalent ions (e.g., with a charge of +2 or +3) have the potential to provide two or more the electrical current of Li-ions (depending on the charge of the multivalent ion) if present with the same density. Calcium ion and magnesium ion provide relatively high potentials (Ca2+: ?2.87 relative to standard hydrogen electrode, SHE; Mg2+: ?2.37 vs. SHE) suitable for many secondary battery requirements. Mg batteries are one of the attractive technological alternatives due to low cost and high abundance of Mg, approximately 2 to 5-folds higher theoretical volumetric capacity of anodes (Mg: 3832 mAh/cm3 vs Li: 2061 mAh/cm3 vs graphite: 777 mAh/cm3) and higher safety associated with non-pyrophoric or dendrite-free Mg metal.

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