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Non-aqueous electrolytic solution for lithium secondary battery or lithium ion capacitor, and lithium secondary battery or lithium ion capacitor using the same

專利號(hào)
US10868336B2
公開日期
2020-12-15
申請(qǐng)人
UBE INDUSTRIES, LTD.(JP Ube)
發(fā)明人
Koji Abe; Makoto Babazono; Masahide Kondo; Hiroshi Yanagi; Kei Shimamoto
IPC分類
H01M10/0569; H01G11/60; H01M10/052; H01G11/06; H01G11/62; H01M4/36; H01M4/505; H01M4/525; H01M10/0525; H01M10/0568; H01M10/0567; H01M4/38; H01M4/58; H01M4/485; H01G11/32; H01G11/50; H01M4/587
技術(shù)領(lǐng)域
aqueous,lithium,lipf6,carbonate,1.1m,non,electrode,in,battery,or
地域: Ube-shi

摘要

The present invention provides a non-aqueous electrolytic solution for a lithium secondary battery or a lithium ion capacitor, wherein the non-aqueous electrolytic solution includes a lithium salt as dissolved in a non-aqueous solvent in a concentration of 0.8 to 1.5 M (mol/L), the non-aqueous solvent includes, in relation to the whole of the non-aqueous solvent, 5 to 25% by volume of ethylene carbonate, 5 to 25% by volume of propylene carbonate, 20 to 30% by volume of dimethyl carbonate, 20 to 40% by volume of methyl ethyl carbonate, and 10 to 20% by volume of a fluorinated chain ester; the total content of ethylene carbonate and propylene carbonate in the non-aqueous solvent is 20 to 30% by volume, the total content of dimethyl carbonate and the fluorinated chain ester in the non-aqueous solvent is 30 to 40% by volume; and the flash point of the non-aqueous electrolytic solution is 20° C. or higher, and the present invention also provides an energy storage device.

說(shuō)明書

Among these, LiPF6, LiPO2F2, LiN(SO2F)2, lithium methyl sulfate, lithium ethyl sulfate, or lithium difluorobis(oxalato)phosphate is preferably used, and LiPF6, LiPO2F2, LiN(SO2F)2, lithium methyl sulfate, or lithium ethyl sulfate is most preferably used. The concentration of the lithium salt in the non-aqueous electrolytic solution according to the first aspect is, in relation to the non-aqueous solvent, 0.8 M (mol/L) or more, preferably 1.0 M or more, and more preferably 1.1 M or more. The upper limit of the concentration of the lithium salt is 1.5 M or less, preferably 1.45 M or less, and more preferably 1.4 M or less. The concentration of the lithium salt in the non-aqueous electrolytic solution according to the second aspect is, in relation to the non-aqueous solvent, 0.9 M (mol/L) or more, preferably 1.0 M or more, more preferably 1.1 M or more, further preferably 1.15 M or more, and particularly preferably 1.2 M or more. The upper limit of the concentration of the lithium salt is 1.5 M or less, preferably 1.45 M or less, and more preferably 1.4 M or less.

權(quán)利要求

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