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Non-aqueous electrolytic solution for lithium secondary battery or lithium ion capacitor, and lithium secondary battery or lithium ion capacitor using the same

專利號
US10868336B2
公開日期
2020-12-15
申請人
UBE INDUSTRIES, LTD.(JP Ube)
發(fā)明人
Koji Abe; Makoto Babazono; Masahide Kondo; Hiroshi Yanagi; Kei Shimamoto
IPC分類
H01M10/0569; H01G11/60; H01M10/052; H01G11/06; H01G11/62; H01M4/36; H01M4/505; H01M4/525; H01M10/0525; H01M10/0568; H01M10/0567; H01M4/38; H01M4/58; H01M4/485; H01G11/32; H01G11/50; H01M4/587
技術(shù)領域
aqueous,lithium,lipf6,carbonate,1.1m,non,electrode,in,battery,or
地域: Ube-shi

摘要

The present invention provides a non-aqueous electrolytic solution for a lithium secondary battery or a lithium ion capacitor, wherein the non-aqueous electrolytic solution includes a lithium salt as dissolved in a non-aqueous solvent in a concentration of 0.8 to 1.5 M (mol/L), the non-aqueous solvent includes, in relation to the whole of the non-aqueous solvent, 5 to 25% by volume of ethylene carbonate, 5 to 25% by volume of propylene carbonate, 20 to 30% by volume of dimethyl carbonate, 20 to 40% by volume of methyl ethyl carbonate, and 10 to 20% by volume of a fluorinated chain ester; the total content of ethylene carbonate and propylene carbonate in the non-aqueous solvent is 20 to 30% by volume, the total content of dimethyl carbonate and the fluorinated chain ester in the non-aqueous solvent is 30 to 40% by volume; and the flash point of the non-aqueous electrolytic solution is 20° C. or higher, and the present invention also provides an energy storage device.

說明書

The non-aqueous electrolytic solution according to the first aspect of the present invention includes a fluorinated chain ester as a chain ester. As the fluorinated chain ester used in the present invention, a chain ester in which an arbitrary carbon atom(s) is substituted with a fluorine atom(s) may be mentioned. In particular, a compound in which the carbon atom(s) in the alkyloxy group moiety of a chain ester is substituted with a fluorine atom(s) may be suitably mentioned.

As the fluorinated chain ester, in particular, the compound represented by the following general formula (I) may be suitably mentioned.

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(In the formula, R1 is CFmH3-m or OCFmH3-m, R2 is CH3, C2H5, or CH2CFnH3-n, m is an integer from 0 to 3, and n represents 2 or 3, with the proviso that either of R1 and R2 is substituted with at least one fluorine atom.)

Suitable specific examples of the fluorinated chain ester represented by the general formula (I) include: one or more selected from the group consisting of 2,2-difluoroethyl acetate (DFEA), 2,2,2-trifluoroethyl acetate (TFEA), 2,2-difluoroethyl methyl carbonate (DFEMC), 2,2,2-trifluoroethyl methyl carbonate (TFEMC), methyl trifluoroacetate, ethyl trifluoroacetate, 2,2-difluoroethyl trifluoroacetate, and 2,2,2-trifluoroethyl trifluoroacetate.

權(quán)利要求

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