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Non-aqueous electrolytic solution for lithium secondary battery or lithium ion capacitor, and lithium secondary battery or lithium ion capacitor using the same

專利號
US10868336B2
公開日期
2020-12-15
申請人
UBE INDUSTRIES, LTD.(JP Ube)
發(fā)明人
Koji Abe; Makoto Babazono; Masahide Kondo; Hiroshi Yanagi; Kei Shimamoto
IPC分類
H01M10/0569; H01G11/60; H01M10/052; H01G11/06; H01G11/62; H01M4/36; H01M4/505; H01M4/525; H01M10/0525; H01M10/0568; H01M10/0567; H01M4/38; H01M4/58; H01M4/485; H01G11/32; H01G11/50; H01M4/587
技術(shù)領(lǐng)域
aqueous,lithium,lipf6,carbonate,1.1m,non,electrode,in,battery,or
地域: Ube-shi

摘要

The present invention provides a non-aqueous electrolytic solution for a lithium secondary battery or a lithium ion capacitor, wherein the non-aqueous electrolytic solution includes a lithium salt as dissolved in a non-aqueous solvent in a concentration of 0.8 to 1.5 M (mol/L), the non-aqueous solvent includes, in relation to the whole of the non-aqueous solvent, 5 to 25% by volume of ethylene carbonate, 5 to 25% by volume of propylene carbonate, 20 to 30% by volume of dimethyl carbonate, 20 to 40% by volume of methyl ethyl carbonate, and 10 to 20% by volume of a fluorinated chain ester; the total content of ethylene carbonate and propylene carbonate in the non-aqueous solvent is 20 to 30% by volume, the total content of dimethyl carbonate and the fluorinated chain ester in the non-aqueous solvent is 30 to 40% by volume; and the flash point of the non-aqueous electrolytic solution is 20° C. or higher, and the present invention also provides an energy storage device.

說明書

In the non-aqueous electrolytic solution according to the second aspect of the present invention, the total content of dimethyl carbonate and ethyl propionate is 30% by volume or more, and preferably 32% by volume or more, in relation to the whole of the non-aqueous solvent, from the viewpoint of the improvement of the electric conductivity. The upper limit of the total content of dimethyl carbonate and ethyl propionate is 40% by volume or less, and preferably 37% by volume or less, in relation to the whole of the non-aqueous solvent, from the viewpoint of the improvement of the electrochemical characteristics in a high temperature environment.

In the non-aqueous electrolytic solution according to the second aspect of the present invention, the total content of the chain carbonate and ethyl propionate is not particularly limited, but the chain carbonate and ethyl propionate are preferably used in a total content range from 70 to 80% by volume in relation to the whole of the non-aqueous solvent. The above-described range is preferable because when the content concerned is 70% by volume or more, the viscosity of the non-aqueous electrolytic solution is not too high, and when the content concerned is 80% by volume or less, the electrochemical characteristics in a wide temperature range due to the decrease of the electric conductivity of the non-aqueous electrolytic solution is less likely to worsen.

權(quán)利要求

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