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Non-aqueous electrolytic solution for lithium secondary battery or lithium ion capacitor, and lithium secondary battery or lithium ion capacitor using the same

專利號(hào)
US10868336B2
公開日期
2020-12-15
申請(qǐng)人
UBE INDUSTRIES, LTD.(JP Ube)
發(fā)明人
Koji Abe; Makoto Babazono; Masahide Kondo; Hiroshi Yanagi; Kei Shimamoto
IPC分類
H01M10/0569; H01G11/60; H01M10/052; H01G11/06; H01G11/62; H01M4/36; H01M4/505; H01M4/525; H01M10/0525; H01M10/0568; H01M10/0567; H01M4/38; H01M4/58; H01M4/485; H01G11/32; H01G11/50; H01M4/587
技術(shù)領(lǐng)域
aqueous,lithium,lipf6,carbonate,1.1m,non,electrode,in,battery,or
地域: Ube-shi

摘要

The present invention provides a non-aqueous electrolytic solution for a lithium secondary battery or a lithium ion capacitor, wherein the non-aqueous electrolytic solution includes a lithium salt as dissolved in a non-aqueous solvent in a concentration of 0.8 to 1.5 M (mol/L), the non-aqueous solvent includes, in relation to the whole of the non-aqueous solvent, 5 to 25% by volume of ethylene carbonate, 5 to 25% by volume of propylene carbonate, 20 to 30% by volume of dimethyl carbonate, 20 to 40% by volume of methyl ethyl carbonate, and 10 to 20% by volume of a fluorinated chain ester; the total content of ethylene carbonate and propylene carbonate in the non-aqueous solvent is 20 to 30% by volume, the total content of dimethyl carbonate and the fluorinated chain ester in the non-aqueous solvent is 30 to 40% by volume; and the flash point of the non-aqueous electrolytic solution is 20° C. or higher, and the present invention also provides an energy storage device.

說明書

The non-aqueous electrolytic solution according to the first aspect of the present invention and the non-aqueous electrolytic solution according to the second aspect of the present invention can each be obtained, for example, by mixing the above-described non-aqueous solvents, and by dissolving the above-described lithium salt in the resulting mixed non-aqueous solvent, and by adding other additives in the resulting non-aqueous electrolytic solution.

In this case, it is preferable that the non-aqueous solvent to be used and the additives to be added to the non-aqueous electrolytic solution are preliminarily purified to the extent that the productivity does not decrease, and the non-aqueous solvents and the additives extremely small in the amounts of impurities are used.

The non-aqueous electrolytic solution according to the first aspect of the present invention and the non-aqueous electrolytic solution according to the second aspect of the present invention can be used in the following lithium secondary battery or the following lithium ion capacitor, and can use as the non-aqueous electrolyte not only liquid non-aqueous electrolytes but also gelled non-aqueous electrolytes. Moreover, the non-aqueous electrolytic solution according to the first aspect of the present invention and the non-aqueous electrolytic solution according to the second aspect of the present invention can also be used for solid polymer electrolytes. In particular, these non-aqueous electrolytic solutions are more preferably used for lithium secondary batteries.

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