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Cell-core for lithium slurry battery, and lithium slurry battery module

專利號
US10868337B2
公開日期
2020-12-15
申請人
BEIJING HAWAGA POWER STORAGE TECHNOLOGY COMPANY LTD.; HEBEI MAYJOY BATTERY COMPANY LTD.(CN Beijing CN Heibei)
發(fā)明人
Yongchong Chen; Yingyuan He; Xiaohu Zhang; Bin Zhang; Caimei Feng; Yanping Zhang; Ping Zhang
IPC分類
H01M2/12; H01M10/058; H01M2/36; H01M2/04; H01M10/052; H01M10/0585; H01M4/13; H01M10/0525; H01M4/72; H01M4/40; H01M4/66; H01M2/10; H01M4/74; H01M4/134; H01M4/04; H01M4/38; H01M4/02
技術領域
lithium,battery,cell,slurry,conductive,electrode,layer,shell,cathode,discharge
地域: Beijing

摘要

Provided is a no-liquid cell-core for a lithium slurry battery. The no-liquid cell-core comprises multiple positive electrode pieces and negative electrode pieces overlapping alternately. The positive electrode piece comprises an electric-conductive cathode layer and a cathode surface current-collecting layer, wherein the electric-conductive cathode layer contains a part or all of the electric-conductive cathode particles in accumulated state without adhesive bonding, and the cathode surface current-collecting layer is set on the surface of the electric-conductive cathode layer and contacted with it tightly. The negative electrode piece comprises an electric-conductive lithium-intercalatable anode layer which is a lithium-containing metal body and/or a layer containing a part or all of electric-conductive lithium-intercalatable anode particles in accumulated state without adhesive bonding. The peripheral edges of the positive electrode piece and/or the negative electrode piece are insulated and sealed. A lithium slurry battery module containing the no-liquid cell-core is also provided.

說明書

The cathode surface current-collecting layer further comprises an interface-improving layer, and the interface-improving layer is combined on the surface of the cathode surface current-collecting layer by one or more methods of vacuum evaporation deposition, magnetron sputtering, plasma deposition, spraying, bonding, mechanical pressing, printing or inkjet printing. The material of the interface-improving layer comprises the conductive agent and the binder, and the mass ratio of the binder to the conductive agent is 0.5 to 20:99.5 to 80. Or the interface-improving layer only comprises the conductive agent. The conductive agent is selected from the group consisting of carbon black, Ketjenblack, graphene, carbon nanotube, carbon fiber, amorphous carbon, metal conductive particle and metal conductive fiber, or a mixture thereof. The material of the metal conductive particle or the metal conductive fiber is aluminum, stainless steel, silver and so on. The binder is selected from the group consisting of polyvinyl chloride, polyethylene, polypropylene, polystyrene, polytetrafluoroethylene, polyterephthalate, polyamide, polyimide, polyether nitrile, polymethyl acrylate, polyvinylidene fluoride, polyurethane, polyacrylonitrile, styrene butadiene rubber, sodium carboxymethyl cellulose and modified polyolefin, or a mixture thereof. The interface-improving layer is tightly coated on the grid of the cathode surface current-collecting layer, capable of improving the interface properties of the cathode surface current-collecting layer and decreasing interface resistance between itself and the electric-conductive cathode layer.

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