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Cell-core for lithium slurry battery, and lithium slurry battery module

專利號
US10868337B2
公開日期
2020-12-15
申請人
BEIJING HAWAGA POWER STORAGE TECHNOLOGY COMPANY LTD.; HEBEI MAYJOY BATTERY COMPANY LTD.(CN Beijing CN Heibei)
發(fā)明人
Yongchong Chen; Yingyuan He; Xiaohu Zhang; Bin Zhang; Caimei Feng; Yanping Zhang; Ping Zhang
IPC分類
H01M2/12; H01M10/058; H01M2/36; H01M2/04; H01M10/052; H01M10/0585; H01M4/13; H01M10/0525; H01M4/72; H01M4/40; H01M4/66; H01M2/10; H01M4/74; H01M4/134; H01M4/04; H01M4/38; H01M4/02
技術(shù)領(lǐng)域
lithium,battery,cell,slurry,conductive,electrode,layer,shell,cathode,discharge
地域: Beijing

摘要

Provided is a no-liquid cell-core for a lithium slurry battery. The no-liquid cell-core comprises multiple positive electrode pieces and negative electrode pieces overlapping alternately. The positive electrode piece comprises an electric-conductive cathode layer and a cathode surface current-collecting layer, wherein the electric-conductive cathode layer contains a part or all of the electric-conductive cathode particles in accumulated state without adhesive bonding, and the cathode surface current-collecting layer is set on the surface of the electric-conductive cathode layer and contacted with it tightly. The negative electrode piece comprises an electric-conductive lithium-intercalatable anode layer which is a lithium-containing metal body and/or a layer containing a part or all of electric-conductive lithium-intercalatable anode particles in accumulated state without adhesive bonding. The peripheral edges of the positive electrode piece and/or the negative electrode piece are insulated and sealed. A lithium slurry battery module containing the no-liquid cell-core is also provided.

說明書

In the no-liquid cell-core, the electric-conductive cathode particles without adhesive bonding and/or the electric-conductive lithium-intercalatable anode particles without adhesive bonding have an accumulation porosity of more than 5% and less than 60%. When immerging in electrolyte, the electric-conductive cathode particles without adhesive bonding and/or electric-conductive lithium-intercalatable anode particles without adhesive bonding can move in the electrolyte and independently form a positive electrode slurry and/or a negative electrode slurry. The electric-conductive cathode particles may account for from 10% to 90% of the mass of the positive electrode slurry, and preferably from 15% to 80%. The electric-conductive lithium-intercalatable anode particles may account for from 10% to 90% of the mass of the negative electrode slurry, and preferably from 15% to 80%. The electric-conductive cathode particles have a mean particle diameter of 0.05 to 500 μm, and the mass ratio of the cathode active material to the conductive agent is 20 to 98:80 to 2; and the electric-conductive lithium-intercalatable anode particles have a mean particle diameter of 0.05 to 500 μm, and the mass ratio of the lithium-intercalatable anode material to the conductive agent is 20 to 98:80 to 2.

The cathode active material may be selected from the group consisting of lithium iron phosphate, lithium manganese phosphate, lithium silicate, lithium iron silicate, sulfate compounds, sulfur carbon composite, sulfur, titanium sulfur compounds, molybdenum sulfur compounds, iron sulfur compounds, lithium-doped manganese oxide, lithium cobalt oxide, lithium titanium oxide, lithium vanadium oxide, lithium nickel manganese oxide, lithium nickel cobalt oxide, lithium nickel cobalt aluminum oxide, lithium nickel aluminum oxide, lithium nickel cobalt manganese oxide and lithium iron nickel manganese oxide, or a mixture thereof.

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