What is claimed is:1. A method, comprising:forming a trench in a low-K dielectric layer, wherein the trench exposes an underlying contact area of a substrate;depositing a first tantalum nitride (TaN) layer conformally within the trench, wherein the first TaN layer is deposited using atomic layer deposition (ALD);depositing a second TaN layer on the first TaN layer conformally with the trench, wherein the second TaN layer is deposited using a different process than the process used to deposit the first TaN layer;depositing a tantalum (Ta) layer on the second TaN layer conformally within the trench, wherein the Ta layer is deposited using physical vapor deposition (PVD);performing an electroplating process to deposit a conductive layer over the Ta layer; andforming a via over the conductive layer, wherein forming the via includes depositing a third TaN layer within the via and in contact with the conductive layer, and wherein the third TaN layer is deposited using ALD;wherein the depositing the first TaN layer and the second TaN layer forms an α-Ta component that spans across a respective thickness of each of the first TaN layer and the second TaN layer.2. The method of claim 1, wherein the first TaN layer and the third TaN layer have a greater concentration of nitrogen than tantalum.3. The method of claim 1, wherein the low-K dielectric layer is disposed at least partially over a silicon nitride cap layer.4. The method of claim 1, wherein an N/Ta ratio of the first TaN layer and the third TaN layer ranges from 2.3 to 2.6.5. The method of claim 1, wherein the depositing of the first TaN layer and the third TaN layer includes plasma sputtering a Ta target with a nitrogen (N2) flow of at least 20 Standard Cubic Centimeters per Minute (sccm).6. The method of claim 1, wherein the first TaN layer and the third TaN layer are deposited to have a thickness ranging from 5 to 10 angstrom (?).7. The method of claim 1, wherein the Ta layer is deposited to have a thickness ranging from 50 to 100 ?.8. The method of claim 1, wherein the performing the electroplating process includes depositing a seed layer prior to depositing the conductive layer.9. The method of claim 1, wherein the conductive layer includes copper (Cu).10. A method, comprising:depositing a dielectric layer on a substrate;forming an opening in the dielectric layer;depositing a first tantalum nitride (TaN) layer within the opening such that the first TaN layer has a greater concentration of nitrogen than tantalum;performing a plurality of physical vapor deposition (PVD) processes to deposit a second TaN layer on the first TaN layer and a tantalum (Ta) layer on the second TaN layer, wherein a controlled nitrogen flow during deposition of the second TaN layer provides for formation of an α-Ta component that spans from a top surface of the second TaN layer to a bottom surface of the second TaN layer; anddepositing a metal layer over the PVD-deposited Ta layer.11. The method of claim 10, wherein the dielectric layer includes a low-K dielectric layer.12. The method of claim 10, wherein the depositing of the first TaN layer includes plasma sputtering a Ta target with a nitrogen (N2) flow ranging from 20 sccm to 40 sccm.13. The method of claim 10, wherein an overall carbon (C) concentration of the first TaN layer and the Ta layer is less than 0.2 percent (%).14. The method of claim 10, wherein the first TaN layer is deposited to have a thickness ranging from 10 to 20 angstrom (?).15. The method of claim 10, wherein the Ta layer is deposited to have a thickness ranging from 50 to 100 ?.16. The method of claim 10, wherein the metal layer includes an electroplated metal layer.17. The method of claim 16, wherein the electroplated metal layer includes copper (Cu).18. A method, comprising:forming a trench in a low-K dielectric layer;conformally depositing a first tantalum nitride (TaN) layer on a side wall of the trench using atomic layer deposition (ALD);depositing a second TaN layer on the first TaN layer using a first physical vapor deposition (PVD) process, wherein the second TaN layer includes an α-Ta component that spans from the top surface to the bottom surface of the second TaN layer; anddepositing a tantalum (Ta) layer on the second TaN layer using a second PVD process;wherein an overall carbon (C) concentration of the first TaN layer and the Ta layer is less than 0.2 percent (%).19. The method of claim 18, wherein an N/Ta ratio of the first TaN layer ranges from 2.3 to 2.6.20. The method of claim 18, wherein the first TaN layer is deposited to have a thickness ranging from 5 to 10 angstrom (?), and the Ta layer is deposited to have a thickness ranging from 50 to 100 ?.