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Method for inkjet printing an organic-inorganic perovskite

專利號
US11177440B2
公開日期
2021-11-16
申請人
AALTO UNIVERSITY FOUNDATION; ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL); SOLARONIX S.A.(FI Helsinki CH Ecublens CH Aubonne)
發(fā)明人
Syed Ghufran Hashmi; Merve Ozkan; David Martineau; Xiong Li; Shaik Mohammed Zakeeruddin; Michael Graetzel
IPC分類
H01L51/42; H01L51/00
技術領域
perovskite,solar,precursor,in,ink,printing,cation,preferably,said,inkjet
地域: Helsinki

摘要

The present invention provides a method for depositing an organic-inorganic perovskite, the method comprising the step of depositing a perovskite precursor solution comprising one or more organic cation, wherein said precursor solution preferably deposited by inkjet printing. The method is particularly useful in the manufacture of perovskite solar cells. For depositing the perovskite, a perovskite precursor solution or ink is preferably used, which comprises an organic cation carrying an anchoring group, such as 5-ammonium valeric acid. Surprisingly, the presence of the latter compound renders the precursor solutions stable and suitable for inkjet printing.

說明書

FIG. 5 shows the J-V curve of a perovskite solar cell fabricated with inkjet infiltration of perovskite precursor ink in accordance with an embodiment of the invention. The active area of the cell was 0.16 cm2 which was defined by the aperture area of the black tape mask.

FIG. 6 shows the results of a one sub soaking test at 35° C. of a batch of nine perovskite solar cells produced in accordance with an embodiment of the invention.

FIG. 7 shows J-V curves of a fresh perovskite solar cell (in blue) and aged (stored in vacuum for 3 weeks, in red), produced in according to embodiments of the invention.

FIG. 8 shows a) Fujifilm's Dimatix inkjet printer (Model DMP-2831) which was used for depositing a perovskite in accordance with an embodiment of the invention, and the b) printer cartridge filled with perovskite precursor ink and used with the device shown in a).

FIG. 9 shows cross-sectional SEM images of triple layer (TiO2/ZrO2/C) perovskite solar cells fabricated in accordance with embodiments of the invention.

FIG. 10 schematically shows the structure of a solar cell according to an embodiment of the invention.

FIG. 11 shows photographs of an ink in accordance with the invention (left vial) compared to an ink with a conventional composition (right vial). Panels a)-b) show front and back views of the vials directly after preparation. Panel c) shows the ink after 20 minutes at room temperature.

權(quán)利要求

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