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Method for inkjet printing an organic-inorganic perovskite

專利號
US11177440B2
公開日期
2021-11-16
申請人
AALTO UNIVERSITY FOUNDATION; ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL); SOLARONIX S.A.(FI Helsinki CH Ecublens CH Aubonne)
發(fā)明人
Syed Ghufran Hashmi; Merve Ozkan; David Martineau; Xiong Li; Shaik Mohammed Zakeeruddin; Michael Graetzel
IPC分類
H01L51/42; H01L51/00
技術(shù)領(lǐng)域
perovskite,solar,precursor,in,ink,printing,cation,preferably,said,inkjet
地域: Helsinki

摘要

The present invention provides a method for depositing an organic-inorganic perovskite, the method comprising the step of depositing a perovskite precursor solution comprising one or more organic cation, wherein said precursor solution preferably deposited by inkjet printing. The method is particularly useful in the manufacture of perovskite solar cells. For depositing the perovskite, a perovskite precursor solution or ink is preferably used, which comprises an organic cation carrying an anchoring group, such as 5-ammonium valeric acid. Surprisingly, the presence of the latter compound renders the precursor solutions stable and suitable for inkjet printing.

說明書

In an embodiment, the “precipitation retarding compound” comprises a group comprising a nitrogen atom, preferably a nitrogen atom present in a positively charged state. Preferably, the nitrogen containing group is represented by the letter “W”, for example as defined elsewhere in this specification. Exemplary groups may be selected from —NH3+, —NH—C(NH3+)═NH, and —N═CH—NH3+. The compound preferably comprises an ammonium group.

In an embodiment, said “precipitation retarding compound” comprises a linker or spaceholder moiety (R1), connecting said anchoring group and said preferably positively charged group, for example said positively charged nitrogen atom.

In an embodiment, said linker moiety is preferably an organic moiety comprising 1-20 carbons and 0-10 heteroatoms, preferably 2-12 carbons and 0-7 heteroatoms, more preferably 3-10 carbons and 0-5 heteroatoms, and most preferably 4-8 carbons and 0 heteroatoms. Said organic moiety may be totally or partially halogenated, in addition to said heteroatoms.

In an embodiment, said linker moiety is preferably a C1-C20 hydrocarbon, preferably a C2-C15 hydrocarbon, more preferably a C3-C12 hydrocarbon, and most preferably a C4-C8 hydrocarbon.

In an embodiment, said linker moiety is preferably selected from the group consisting of a C1-C20 alkanediyl, C2-C20 alkynediyl, C2-C20 alkynediyl, C4-C20 heteroaryldiyl, and C6-C20 aryldiyl, preferably C2-C15 alkanediyl, C2-C15 alkynediyl, C2-C15 alkynediyl, C4-C15 heteroaryldiyl, and C6-C15 aryldiyl, more preferably C3-C12 alkanediyl, C3-C12 alkynediyl, C3-C20 alkynediyl, C4-C12 heteroaryldiyl, and C6-C12 aryldiyl, most preferably C4-C8 alkanediyl, C4-C8 alkynediyl, C4-C8 alkynediyl, C4-C8 heteroaryldiyl, and C6-C8 aryldiyl.

權(quán)利要求

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