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Method for inkjet printing an organic-inorganic perovskite

專利號
US11177440B2
公開日期
2021-11-16
申請人
AALTO UNIVERSITY FOUNDATION; ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL); SOLARONIX S.A.(FI Helsinki CH Ecublens CH Aubonne)
發(fā)明人
Syed Ghufran Hashmi; Merve Ozkan; David Martineau; Xiong Li; Shaik Mohammed Zakeeruddin; Michael Graetzel
IPC分類
H01L51/42; H01L51/00
技術(shù)領(lǐng)域
perovskite,solar,precursor,in,ink,printing,cation,preferably,said,inkjet
地域: Helsinki

摘要

The present invention provides a method for depositing an organic-inorganic perovskite, the method comprising the step of depositing a perovskite precursor solution comprising one or more organic cation, wherein said precursor solution preferably deposited by inkjet printing. The method is particularly useful in the manufacture of perovskite solar cells. For depositing the perovskite, a perovskite precursor solution or ink is preferably used, which comprises an organic cation carrying an anchoring group, such as 5-ammonium valeric acid. Surprisingly, the presence of the latter compound renders the precursor solutions stable and suitable for inkjet printing.

說明書

The advantages of the present invention are most apparent if the precursor solution comprises all components required to form said organic-inorganic perovskite, because in this case there is generally an increased risk of undesired crystal formation, for example before application of the precursor solution. In the case of a printing ink, the crystal formation may occur on surface of the ink cartridge, at the nozzle, resulting in clogging of the nozzle. In particular, the invention addresses the problem of providing a perovskite precursor solution that is stable and suitable for printing techniques, such as inkjet printing.

In an embodiment, said precursor solution further comprises an inorganic cation, preferably a metal cation, and anions required for forming said organic-inorganic perovskite.

In accordance with the above, the perovskite precursor solution preferably comprises an inorganic cation, preferably a metal cation that will be present in the perovskite to be deposited.

In an embodiment, the inorganic cation is selected from divalent and trivalent metal cations, depending on the perovskite to be produced. In an embodiment, the inorganic cation is selected from the group consisting of Cu2+, Ni2+, Co2+, Fe2+, Mn2+, Cr2+, Pd2+, Zn2+, Cd2+, Ge2+, Sn2+, Pb2+, Eu2+, Yb2+, Bi3+ and Sb3+ and a combination of two or more of said metal cations.

權(quán)利要求

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