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Method for inkjet printing an organic-inorganic perovskite

專利號(hào)
US11177440B2
公開日期
2021-11-16
申請(qǐng)人
AALTO UNIVERSITY FOUNDATION; ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL); SOLARONIX S.A.(FI Helsinki CH Ecublens CH Aubonne)
發(fā)明人
Syed Ghufran Hashmi; Merve Ozkan; David Martineau; Xiong Li; Shaik Mohammed Zakeeruddin; Michael Graetzel
IPC分類
H01L51/42; H01L51/00
技術(shù)領(lǐng)域
perovskite,solar,precursor,in,ink,printing,cation,preferably,said,inkjet
地域: Helsinki

摘要

The present invention provides a method for depositing an organic-inorganic perovskite, the method comprising the step of depositing a perovskite precursor solution comprising one or more organic cation, wherein said precursor solution preferably deposited by inkjet printing. The method is particularly useful in the manufacture of perovskite solar cells. For depositing the perovskite, a perovskite precursor solution or ink is preferably used, which comprises an organic cation carrying an anchoring group, such as 5-ammonium valeric acid. Surprisingly, the presence of the latter compound renders the precursor solutions stable and suitable for inkjet printing.

說明書

US2015/0242444 discloses photovoltaic perovskite devices comprising optional additives. Several perovskite deposition methods are mentioned in this reference. The reference focuses on the presence of an interfacial layer for enhancing charge transport and preventing charge recombination. In summary, this reference is substantially concerned with perovskite solar cell architectures allowing maximizing the power conversion efficiency.

EP2966703 discloses organic inorganic perovskite heterojunction photovoltaic devices wherein 5-amoniumvaleric acid iodide is used as a templating agent for enhancing crystal growth of the perovskite, device performance and stability.

The perovskite precursor solutions that have been proposed previously all have the drawback that said solutions, when getting in contact with a surface, for example of a glass vial or printing cartridge, rapidly precipitate, such that said solution cannot be applied by way of printing techniques.

For the purpose of the present invention, enhanced crystal growth of the perovskite is a disadvantage if crystal growth and thus precipitation occurs too early, in particular in the printing cartridge, at the printing nozzle, or indeed at any moment before complete infiltration of a porous surface increasing layer or a porous photoanode.

權(quán)利要求

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