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Thermally activated delayed fluorescence material and organic light emitting diode display device

專利號(hào)
US11177442B1
公開日期
2021-11-16
申請(qǐng)人
WUHAN CHINA STAR OPTOELECTRONICS SEMICONDUCTOR DISPLAY TECHNOLOGY CO., LTD.(CN Hubei)
發(fā)明人
Jiajia Luo; Qu Zhang
IPC分類
C09K11/06; C07D401/14; H01L51/00; H01L51/50
技術(shù)領(lǐng)域
mmol,delayed,thermally,1h,2h,organic,bottle,reaction,ml,neck
地域: Hubei

摘要

A thermally activated delayed fluorescent material includes a structural formula (I) as follows: and D1 and D2 are different electron donors. In addition, an organic light emitting diode display device includes an anode, a cathode, and an organic functional layer disposed between the anode and the cathode. The organic functional layer includes a thermally activated delayed fluorescent material, and the thermally activated delayed fluorescent material includes a structural formula (I).

說明書

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BACKGROUND OF INVENTION Field of Invention

The present invention relates to a field of organic electroluminescent materials, and more particularly to a thermally activated delayed fluorescence material and an organic light emitting diode display device.

Description of Prior Art

Dominant guest luminescent materials are critical for affecting luminescent efficiency of organic light emitting diode (OLED) display devices. Generally, the luminescent guest materials used in OLED display devices are fluorescence materials. Generally, a ratio of singlet excitons to triplet excitons in the OLED display devices is 1:3, so an internal quantum efficiency (IQE) of the OLED display devices is merely 25%. Therefore, application of fluorescent electroluminescent devices is greatly limited. The phosphorescent heavy-metal complexes can achieve 100% IQE by using singlet and triplet excitons simultaneously due to the spin-orbit coupling of heavy atoms. However, the used heavy-metals are precious metals, such as iridium (Ir) or platinum (Pt). The phosphorescent heavy-metal complexes must be improved in terms of blue light materials. In addition, pure organic thermally activated delayed fluorescence materials have a lowest single-triplet level difference (ΔEST) which is relatively less than ever before, so that triplet excitons can be transformed to a singlet state by reverse intersystem crossing (RISC) and then are illuminated when jumping to a ground state transition by radiation. Therefore, single and triplet excitons can be simultaneously used and achieve 100% IQE.

權(quán)利要求

1
What is claimed is:1. A thermally activated delayed fluorescent material, comprising a structural formula (I) as follows:embedded imagewherein D1 and D2 are different electron donors.2. The thermally activated delayed fluorescent material according to claim 1, wherein the D1 comprises one of following chemical structural formulas:embedded imagewherein R1 is selected one from an oxygen or a C1-C3 alkyl group;embedded imagewherein the R2 selected one from a C1-C3 alkyl or a silane group;embedded image3. The thermally activated delayed fluorescent material according to claim 1, wherein the D1 is selected one from the group consisting ofembedded image4. The thermally activated delayed fluorescent material according to claim 1, wherein the D2 has a structural formula (I) as follows:embedded imagewherein the R3 is selected one from a hydrogen, a C1-C4 alkyl, an alkoxy, or an aryl.5. The thermally activated delayed fluorescent material according to claim 4, wherein the D2 is selected one from the group consisting ofembedded image6. An organic light emitting diode display device, comprising an anode, a cathode, and an organic functional layer disposed between the anode and the cathode, wherein the organic functional layer comprises a thermally activated delayed fluorescent material, and the thermally activated delayed fluorescent material comprises a structural formula (I) as follows:embedded imagewherein the D1 is selected one from the group consisting ofembedded imageD2 is selected one from the group consisting ofembedded image7. The organic light emitting diode display device according to claim 6, wherein the thermally activated delayed fluorescent material is a fluorescent host material used in the organic light emitting diode display device.8. The organic light emitting diode display device according to claim 6, wherein the thermally activated delayed fluorescent material is an electron transporting material used in the organic light emitting diode display device.9. A thermally activated delayed fluorescent material, comprising a structural formula (I) as follows:embedded imagewherein D1 and D2 are different electron donors, and the D1 comprises one of following chemical structural formulas:embedded imagewherein R1 is selected one from an oxygen or a C1-C3 alkyl group;embedded imagewherein the R2 selected one from a C1-C3 alkyl or a silane group;embedded imageandthe D2 has a structural formula (I) as follows:embedded imagewherein the R3 is selected one from a hydrogen, a C1-C4 alkyl, an alkoxy, or an aryl.10. The thermally activated delayed fluorescent material according to claim 9, wherein the D1 is selected one from the group consisting ofembedded image11. The thermally activated delayed fluorescent material according to claim 9,wherein the D2 is selected one from the group consisting ofembedded image12. The thermally activated delayed fluorescent material according to claim 9, wherein the organic functional layer comprises a thermally activated delayed fluorescent material.13. The thermally activated delayed fluorescent material according to claim 9, wherein the thermally activated delayed fluorescent material is a fluorescent host material used in the organic light emitting diode display device.14. The thermally activated delayed fluorescent material according to claim 9, wherein the thermally activated delayed fluorescent material is an electron transporting material used in the organic light emitting diode display device.
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