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Organic electroluminescent device

專利號
US11177444B2
公開日期
2021-11-16
申請人
LG CHEM, LTD.(KR Seoul)
發(fā)明人
Dongheon Kim; Kongkyeom Kim; Hyungjin Lee; Nansra Heo; Woochul Lee
IPC分類
C07C15/28; C07D471/10; C07D251/24; H01L51/00; H01L51/50; C07D307/91; C09K11/06
技術(shù)領(lǐng)域
group,or,aryl,heteroaryl,atoms,carbon,alkyl,layer,host,material
地域: Seoul

摘要

The present specification relates to an organic electroluminescent device comprising: a first electrode; a second electrode; and an organic material layer provided between the first electrode and the second electrode, wherein the organic material layer comprises a light emitting layer and an electron transfer layer, the light emitting layer comprises a first host material, a second host material and a dopant material, the first host material has a HOMO energy level of ?5.9 eV or lower, and the second host material has a HOMO energy level higher than a HOMO energy level of the first host material by 0.1 eV to 0.2 eV.

說明書

A hole transfer layer was formed on the hole injection layer by vacuum depositing 4-4′-bis[N-(1-naphthyl)-N-phenylamino]biphenyl (NPB) (300 ?), a material transferring holes.

Subsequently, an electron blocking layer was formed on the hole transfer layer to a film thickness of 100 ? by vacuum depositing the following TCTA.

Subsequently, a light emitting layer was formed on the electron blocking layer to a film thickness of 200 ? by vacuum depositing Compound P4 synthesized in Preparation Example 4 and Compound P5 synthesized in Preparation Example 5 as a host, and a pyrene-based dopant of PL Max 452 nm.

On the light emitting layer, an electron injection and transfer layer was formed to a thickness of 300 ? by vacuum depositing Compound P1 synthesized in Preparation Example 1. A cathode was formed on the electron injection and transfer layer by depositing lithium fluoride (LiF) to a thickness of 10 ? and aluminum to a thickness of 1,000 ? in consecutive order.

An organic electroluminescent device was manufactured by maintaining, in the above-mentioned processes, the deposition rates of the organic materials at 0.4 ?/sec to 1 ?/sec, the deposition rates of the lithium fluoride and the aluminum of the cathode at 0.5 ?/sec and 2 ?/sec, respectively, and the degree of vacuum during the deposition at 5×10?8 torr to 8×10?8 torr.

Example 2

An organic electroluminescent device was manufactured in the same manner as in Example 1 except that Compound P6 and Compound P5 were used as the host material.

Comparative Example 1

An organic electroluminescent device was manufactured in the same manner as in Example 1 except that only Compound P5 was used as the host material.

權(quán)利要求

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