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Organoelectroluminescent element, and light emission device, display device, and illumination device in which said organoelectroluminescent element is used

專利號
US11177450B2
公開日期
2021-11-16
申請人
Naoyuki Hayashi; Hideki Yasuda; Koji Takaku(IE Dublin)
發(fā)明人
Naoyuki Hayashi; Hideki Yasuda; Koji Takaku
IPC分類
H01L51/50; H01L51/00
技術(shù)領(lǐng)域
group,layer,atom,preferably,emitting,ligand,ring,light,nm,in
地域: Kanagawa

摘要

An organoelectroluminescent element which can satisfy both a high external quantum efficiency and high power efficiency at the same time, which has on a substrate an anode, a first intermediate organic layer composed of at least one organic layer, a light-emitting layer, a second intermediate organic layer composed of at least one organic layer, and a cathode in this order, and in which light is extracted from the aforementioned anode side, wherein the aforementioned light-emitting layer contains a light-emitting material that is oriented in the horizontal direction with the substrate, the order parameter of the aforementioned light-emitting material in the aforementioned light-emitting layer is at least 0.7, and the relationship between the thickness T1 (nm) of the aforementioned first intermediate organic layer and the thickness T2 (nm) of the aforementioned second intermediate organic layer is such that 1.1

說明書

Over this, lithium fluoride was vapor-deposited in a thickness of 1 nm, followed by metallic aluminum in a thickness of 70 nm, which gave a cathode. Note that the lithium fluoride (1 nm) constitutes a layer located between the light-emitting layer and the cathode, but because it is an inorganic layer, it is not included in the thickness of the second intermediate organic layer of the present application.

This laminate was put in a glove box that had been replaced with nitrogen gas without coming into contact with the air, and was sealed using a glass sealing jar and a UV-setting adhesive (XNR5516HV, made by Nagase Chiba), which gave the element of Working Example 9.

Comparative Example 13

Other than changing as follows, the element of Comparative Example 13 was obtained in the same manner as in Working Example 9:

First layer (hole injection layer): HIL-2; film thickness of 95 nm

Second layer (hole transport layer): HTL-2; film thickness of 30 nm

The external quantum efficiency and the power efficiency of the elements of Working Example 9 and Comparative Example 13 were calculated in the same manner as in Working Example 1. Relative values with the results of Comparative Example 13 being used as the references are given in Table 8 below along with the order parameter (degree of orientation (S)) of the light-emitting material as well as the T1, the T2, the T1/T2 value, and the maximum emission wavelength of the light-emitting material, for each element.

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