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Devices, structures, materials and methods for vertical light emitting transistors and light emitting displays

專利號(hào)
US11177465B2
公開日期
2021-11-16
申請(qǐng)人
Atom H2O, LLC(US CA Escondido)
發(fā)明人
Huaping Li
IPC分類
H01L33/00; H01L51/52; H01L51/56; H01L51/05; H01L27/15; H01L27/32; H01L33/06; H01L33/24; H01L33/28; H01L33/30; H01L33/32; H01L33/34; H01L33/40; H01L33/52; H01L51/00; H01L33/08
技術(shù)領(lǐng)域
nw,ag,vplets,electrode,conductive,electrodes,porous,emitting,dielectric,leps
地域: CA CA Escondido

摘要

Devices, structures, materials and methods for vertical light emitting transistors (VLETs) and light emitting displays (LEDs) are provided. In particular, architectures for vertical polymer light emitting transistors (VPLETs) for active matrix organic light emitting displays (AMOLEDs) and AMOLEDs incorporating such VPLETs are described. Porous conductive transparent electrodes (such as from nanowires (NW)) alone or in combination with conjugated light emitting polymers (LEPs) and dielectric materials are utilized in forming organic light emitting transistors (OLETs). Combinations of thin films of ionic gels, LEDs, porous conductive electrodes and relevant substrates and gates are utilized to construct LETs, including singly and doubly gated VPLETs. In addition, printing processes are utilized to deposit layers of one or more of porous conductive electrodes, LEDs, and dielectric materials on various substrates to construct LETs, including singly and doubly gated VPLETs.

說明書

As shown in FIG. 9a, in this exemplary embodiment, a printed Ag NW enabled VPLET is proposed comprised of printed Ag NW networks as a porous conductive Source electrode, LEPs (blue: PFO, green: super yellow, red: MEH-PPV) as channel materials (PLED), PEDOT/PSS coated ITO as a Drain electrode, and SiO2 as the dielectric layer for gate modulation. Using aerosol jet printing, uniform and thin-layer Ag NW networks and 200 nm LEPs (blue: PFO, green: super-yellow, red: MEH-PPV) may be printed in various substrates. The sheet resistance of printed Ag NW networks is about 15Ω/sq. Its SEM image is shown in FIG. 9b, exhibiting great uniformity. The porous structure of Ag NW networks permits the direct contact between LEPs and SiO2 dielectric layer. FIG. 9b also shows a photograph of a printed MEH-PPV polymer with a uniform surface that is essential for organic devices. In this embodiment, by laminating PEDOT/PSS coated ITO with printed MEH-PPV on Silicon wafer, Ag NW enabled VPLETs with an ITO electrode on silicon wafer may be fabricated. Alternatively, printed Ag NW networks can be laminated with MEH-PPV fabricated on ITO by slight pressing and thermal treatment. To improve the performance of Ag NW enabled VPLETs, it is also possible to coat the SiO2 layer with octyltriethoxysiliane (OTS) to improve the gate modulation and treating Ag NW network with CPE or polyethylimine (PEI) to enhance electron injection. The printed Ag NW enabled VPLETs may be characterized in a glovebox using a Keithley 4200 Semiconductor Characterization System (SCS). Using such process it is possible to fabricate Ag NW enabled VPLETs with characteristics outperforming those of PLEDs, with low supply and driving voltages, and full aperture ratio.

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