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Devices, structures, materials and methods for vertical light emitting transistors and light emitting displays

專利號
US11177465B2
公開日期
2021-11-16
申請人
Atom H2O, LLC(US CA Escondido)
發(fā)明人
Huaping Li
IPC分類
H01L33/00; H01L51/52; H01L51/56; H01L51/05; H01L27/15; H01L27/32; H01L33/06; H01L33/24; H01L33/28; H01L33/30; H01L33/32; H01L33/34; H01L33/40; H01L33/52; H01L51/00; H01L33/08
技術(shù)領(lǐng)域
nw,ag,vplets,electrode,conductive,electrodes,porous,emitting,dielectric,leps
地域: CA CA Escondido

摘要

Devices, structures, materials and methods for vertical light emitting transistors (VLETs) and light emitting displays (LEDs) are provided. In particular, architectures for vertical polymer light emitting transistors (VPLETs) for active matrix organic light emitting displays (AMOLEDs) and AMOLEDs incorporating such VPLETs are described. Porous conductive transparent electrodes (such as from nanowires (NW)) alone or in combination with conjugated light emitting polymers (LEPs) and dielectric materials are utilized in forming organic light emitting transistors (OLETs). Combinations of thin films of ionic gels, LEDs, porous conductive electrodes and relevant substrates and gates are utilized to construct LETs, including singly and doubly gated VPLETs. In addition, printing processes are utilized to deposit layers of one or more of porous conductive electrodes, LEDs, and dielectric materials on various substrates to construct LETs, including singly and doubly gated VPLETs.

說明書

FIG. 11 exhibits the obtained transparent conductive Ag NW PUA film. As shown, a PS-PMMA-PS/EMIM TFSI ionic gel will be printed on the fabricated Ag NW transparent conductive film (TCF) to act as the dielectric layer. PS-PMMA-PS/EMIM TFSI has demonstrated high conductance from P3HT (poly(3-hexylthiophene)) TFTs for driving OLEDs at 4 V support voltage and sub-1 V driving voltage. (See, e.g., J. H. Cho, et al., Nature Materials, vol. 7, pp. 900-906, 2008; Y. Xia, et al., Advanced Functional Materials, vol. 20, pp. 587-594, 2010; and D. Braga , et al., Advanced Functional Materials, vol. 22, pp. 1623-1631, 2012, the disclosures of which are incorporated herein by reference.) The ionic liquid can penetrate into the active layer, which will behave as a light emitting electrochemical cell (LEC). (See, e.g., Q. Pei, et al., Science, vol. 269, pp. 1086-1088, 1995, the disclosure of which is incorporated herein by reference.) Printed PS-PMMA-PS/EMIM TFSI ionic gel on Ag NW TCF will be stacked on printed Ag NW networks on a glass slide. After drying PS-PMMA-PS/EMIM TFSI ionic gel, Ag NW TCF will be peeled off from the glass slide to obtain a Ag NW electrodes sandwiched ionic gel. PEDOT/PSS will be printed on another fabricated Ag NW transparent conductive film. After drying a PEDOT/PSS coated Ag NW film under vacuum, 200 nm thick LEPs (blue: PFO, green: super-yellow, red: MEH-PPV) will be printed to serve as the active layers.

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