白丝美女被狂躁免费视频网站,500av导航大全精品,yw.193.cnc爆乳尤物未满,97se亚洲综合色区,аⅴ天堂中文在线网官网

High-compacted-density positive electrode material and electrochemical energy storage apparatus

專利號(hào)
US11177468B2
公開日期
2021-11-16
申請(qǐng)人
CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED(CN Ningde)
發(fā)明人
Rui Du; Yongchao Liu; Deyu Zhao; Na Liu
IPC分類
H01M4/131; H01M4/134; H01M4/505; H01M4/525; H01M10/0525; C01G53/00; H01M4/02
技術(shù)領(lǐng)域
lithium,nickel,transition,oxide,electrode,positive,metal,μm,particle,δpsd
地域: Ningde

摘要

This application relates to the field of battery technologies, and in particular, to a high-compacted-density positive electrode material and an electrochemical energy storage apparatus. The positive electrode material includes a lithium-nickel transition metal oxide A and a lithium-nickel transition metal oxide B. The lithium-nickel transition metal oxide A is secondary particles, whose chemical formula is shown in formula I: Lia1(Nib1Coc1Mnd1)x1M1-x1O2-e1Xe1. The lithium-nickel transition metal oxide B is a monocrystalline structure or a monocrystalline-like structure, whose chemical formula is shown in formula II: Lia2(Nib2Coc2Mnd2)x2M′1-x2O2-e2X′e2 (II). The positive electrode material of this application includes the large-particle lithium-nickel transition metal oxide A and the small-particle lithium-nickel transition metal oxide B to improve an energy density of the battery. A degree of crystallinity and particle size distribution of the mixed positive electrode material can improve a compacted density of the high-nickel active material, and ensure lower gassing and good cycle performance.

說(shuō)明書

In the positive electrode material in this application, the lithium-nickel transition metal oxide A has a single-particle pressure-resistant strength of ≥100 MPa and the lithium-nickel transition metal oxide B has a single-particle pressure-resistant strength of ≥50 MPa. In this application, the lithium-nickel transition metal oxides with such two single-particle pressure-resistant strengths are mixed to obtain the positive electrode material, so as to improve the pressure-resistant performance of the entire positive electrode material. The monocrystalline/monocrystalline-like particles with a small particle size are mainly used to fill the gap between the secondary-particle powder with a large particle size, and withstand relatively small force; however, may be still crushed under the action of swelling of electrode plates or external force when the pressure-resistant strength is excessively low. The secondary particles with a larger particle size withstand most of the external force during the swelling or pressing of the electrode plates. Because there are a large quantity of crystalline boundaries inside the secondary particles, microcracks easily occur under the external force or during cycling. In this application, the mixed positive electrode material of the lithium-nickel transition metal oxide B with the single-particle pressure-resistant strength of ≥50 MPa and the lithium-nickel transition metal oxide A with the single-particle pressure-resistant strength of ≥100 MPa is selected to ensure that the pressure-resistant performance of the positive electrode material obtained through mixing can adapt to the external force during electrode plate preparation and cycling. In some embodiments, the single-particle pressure-resistant strength of the lithium-nickel transition metal oxide A is higher than the single-particle pressure-resistant strength of the lithium-nickel transition metal oxide B.

權(quán)利要求

1
微信群二維碼
意見(jiàn)反饋