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High-compacted-density positive electrode material and electrochemical energy storage apparatus

專利號
US11177468B2
公開日期
2021-11-16
申請人
CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED(CN Ningde)
發(fā)明人
Rui Du; Yongchao Liu; Deyu Zhao; Na Liu
IPC分類
H01M4/131; H01M4/134; H01M4/505; H01M4/525; H01M10/0525; C01G53/00; H01M4/02
技術領域
lithium,nickel,transition,oxide,electrode,positive,metal,μm,particle,δpsd
地域: Ningde

摘要

This application relates to the field of battery technologies, and in particular, to a high-compacted-density positive electrode material and an electrochemical energy storage apparatus. The positive electrode material includes a lithium-nickel transition metal oxide A and a lithium-nickel transition metal oxide B. The lithium-nickel transition metal oxide A is secondary particles, whose chemical formula is shown in formula I: Lia1(Nib1Coc1Mnd1)x1M1-x1O2-e1Xe1. The lithium-nickel transition metal oxide B is a monocrystalline structure or a monocrystalline-like structure, whose chemical formula is shown in formula II: Lia2(Nib2Coc2Mnd2)x2M′1-x2O2-e2X′e2 (II). The positive electrode material of this application includes the large-particle lithium-nickel transition metal oxide A and the small-particle lithium-nickel transition metal oxide B to improve an energy density of the battery. A degree of crystallinity and particle size distribution of the mixed positive electrode material can improve a compacted density of the high-nickel active material, and ensure lower gassing and good cycle performance.

說明書

8 80 Monocrystalline 3 68 7:3 111 LiNi0.96Co0.02Mn0.02O2 LiNi0.70Co0.15Mn0.15O2 Example 9 Polycrystalline 10 124 Monocrystalline 3 89 7:3 101 Li(Ni0.8Co0.1Mn0.1)0.995Zr0.005O2 LiNi0.8Co0.1Mn0.1O2 Example 10 Polycrystalline 10 120 Monocrystalline 3 85 7:3 110 LiNi0.8Co0.1Mn0.1O2 LiNi0.8Co0.1Mn0.1)0.995Zr0.005O2 Example 11 Polycrystalline 10 115 Monocrystalline 3 89 7:3 109 LiNi0.8Co0.1Mn0.1O1.99F0.01 LiNi0.8Co0.1Mn0.1O2 Example 12 Polycrystalline 10 120 Monocrystalline 3 84 7:3 109 LiNi0.8Co0.1Mn0.1O2

權利要求

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