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Anode materials for lithium ion batteries and methods of making and using same

專利號
US11177471B2
公開日期
2021-11-16
申請人
JOHNSON MATTHEY PUBLIC COMPANY LIMITED(GB London)
發(fā)明人
Fuxia Sun
IPC分類
H01M4/36; H01M4/62; H01M10/0525; H01M4/134; H01M4/38; C22C24/00; C22C28/00; H01M4/02
技術(shù)領(lǐng)域
alloy,no3,silicon,ee,wt,electrode,lipaa,lithium,metal,coated
地域: London

摘要

An electrochemically active material includes a silicon alloy material having the formula: SiwM1xCyOz, where w, x, y, and z represent atomic % values and w+x+y+z=1; M1 comprises a transition metal; w>0; x>0; y≥0; and z≥0. The electrochemically active material also includes a metal-based material having the formula: M2aObAc, where a, b, and c represent atomic % values and a+b+c=1; M2 comprises a metal; A is an anion; a>0; b≥0; and c≥0.

說明書

Example 67 (E-67): Silicon Alloy E Composite Electrode

Metal based material coated silicon alloy anode materials using silicon alloy E were prepared in a similar fashion according to the procedure outlined in the preparation of metal based material coated silicon alloy B. See Table 11 for the weights of each precursor.

The metal based material coated silicon alloy E was then mixed with, a respective graphite composition, LiPAA, and deionized water using a MAZERUSTAR mixer for 18 min (Table 12). The resulting slurry was then coated onto a 15 μm copper foil using a coating bar with a 0.006″ gap and dried over 2 h in the air. The drying coatings were calendered to 30% porosity according to the calculation. After the calendar, the coatings were further dried under vacuum at 120° C. for 2 h. The final dried coating composition ratio of EE-67 4.5 wt % Cu2(OH)3(NO3) coated silicon alloy E/MAGE/KS6/LiPAA was 30/50/10/10. Coin cell electrodes were then punched from the foil.

TABLE 11* Metal Based Material Coated Silicon Alloy E

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