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Electrocatalyst composition comprising noble metal oxide supported on tin oxide

專利號(hào)
US11177483B2
公開日期
2021-11-16
申請(qǐng)人
BASF SE(DE Ludwigshafen am Rhein)
發(fā)明人
Andreas Haas; Domnik Bayer; Rosalba Adriana Rincon-Ovalles; Markus Kohl
IPC分類
H01M4/90; H01M4/92; C25B11/093; C25B11/097
技術(shù)領(lǐng)域
iridium,tin,oxide,ruthenium,noble,bet,catalyst,m2,ato,sb
地域: Ludwigshafen am Rhein

摘要

The present invention relates to a catalyst composition, comprising tin oxide particles which are at least partially coated by a noble metal oxide layer, wherein the composition contains iridium and ruthenium in a total amount of from 10 wt % to 38 wt %, and all iridium and ruthenium is oxidized, —has a BET surface area of from 5 to 95 m2/g, and —has an electrical conductivity at 25° C. of at least 7 S/cm.

說(shuō)明書

As indicated above, the catalyst composition of the present invention has a BET surface area of from 5 to 95 m2/g. By keeping BET surface area on a moderate level, the tin oxide particles are efficiently covered by a noble metal oxide layer even at relatively low amounts of noble metal.

Preferably, the BET surface area of the composition is from 5 m2/g to 90 m2/g, more preferably from 10 m2/g to 80 m2/g. Even if the BET surface area of the composition is within the range of from 5 m2/g to 60 m2/g, or from 5 m2/g to 50 m2/g, the catalyst composition still shows a surprisingly high catalytic activity. In another preferred embodiment, the BET surface area of the composition is from 5 m2/g to 35 m2/g, in particular if the tin oxide is non-doped.

As indicated above, the catalyst composition has an electrical conductivity at 25° C. of at least 7 S/cm. High electrical conductivity promotes electron transfer to the reactants during the catalytic reaction.

Preferably, the electrical conductivity of the composition is at least 10 S/cm, more preferably at least 12 S/cm. Appropriate ranges are e.g. from 7 to 60 S/cm, more preferably from 10 to 50 S/cm, or from 12 to 40 S/cm.

Preferably, the ratio of the BET surface area (in m2/g) of the composition to the total amount (in wt %) of iridium and ruthenium in the composition is within the range of from 6.0 to 0.75, more preferably 4.0 to 1.0.

權(quán)利要求

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