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Electrocatalyst composition comprising noble metal oxide supported on tin oxide

專利號
US11177483B2
公開日期
2021-11-16
申請人
BASF SE(DE Ludwigshafen am Rhein)
發(fā)明人
Andreas Haas; Domnik Bayer; Rosalba Adriana Rincon-Ovalles; Markus Kohl
IPC分類
H01M4/90; H01M4/92; C25B11/093; C25B11/097
技術(shù)領(lǐng)域
iridium,tin,oxide,ruthenium,noble,bet,catalyst,m2,ato,sb
地域: Ludwigshafen am Rhein

摘要

The present invention relates to a catalyst composition, comprising tin oxide particles which are at least partially coated by a noble metal oxide layer, wherein the composition contains iridium and ruthenium in a total amount of from 10 wt % to 38 wt %, and all iridium and ruthenium is oxidized, —has a BET surface area of from 5 to 95 m2/g, and —has an electrical conductivity at 25° C. of at least 7 S/cm.

說明書

In a preferred embodiment, the tin oxide is doped with antimony in an amount of from 2.5 at % to 20 at %, more preferably from 2.5 at % to 10.0 at %; the amount of iridium in the composition is within the range of from 15 to 35 wt %, more preferably from 20 to 28 wt %, the remainder being the tin oxide particles and the oxygen of the iridium oxide layer; the BET surface area of the composition is from 15 m2/g to 90 m2/g, more preferably from 30 m2/g to 80 m2/g; and the electrical conductivity of the composition is at least 10 S/cm, more preferably at least 12 S/cm (e.g. 10 to 50 S/cm, or 12 to 40 S/cm).

In another preferred embodiment, the tin oxide is a non-doped tin oxide; the amount of iridium in the composition is within the range of from 15 to 35 wt %, more preferably from 20 to 28 wt %, the remainder being the tin oxide particles and the oxygen of the iridium oxide layer; the BET surface area of the composition is from 5 m2/g to 35 m2/g; and the electrical conductivity of the composition is at least 10 S/cm, more preferably at least 12 S/cm (e.g. 10 to 50 S/cm, or 12 to 40 S/cm).

Furthermore, the present invention relates to a process for preparing the catalyst composition as described above, which comprises

    • dispersing tin oxide particles and dissolving a noble-metal-containing precursor compound in an aqueous medium, wherein the noble metal is iridium or ruthenium or a mixture thereof,
    • adjusting pH of the aqueous medium to 5-10 and optionally heating the aqueous medium to a temperature of from 50° C. to 95° C., thereby depositing noble metal species on the tin oxide particles,

權(quán)利要求

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