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Electrocatalyst composition comprising noble metal oxide supported on tin oxide

專利號(hào)
US11177483B2
公開(kāi)日期
2021-11-16
申請(qǐng)人
BASF SE(DE Ludwigshafen am Rhein)
發(fā)明人
Andreas Haas; Domnik Bayer; Rosalba Adriana Rincon-Ovalles; Markus Kohl
IPC分類
H01M4/90; H01M4/92; C25B11/093; C25B11/097
技術(shù)領(lǐng)域
iridium,tin,oxide,ruthenium,noble,bet,catalyst,m2,ato,sb
地域: Ludwigshafen am Rhein

摘要

The present invention relates to a catalyst composition, comprising tin oxide particles which are at least partially coated by a noble metal oxide layer, wherein the composition contains iridium and ruthenium in a total amount of from 10 wt % to 38 wt %, and all iridium and ruthenium is oxidized, —has a BET surface area of from 5 to 95 m2/g, and —has an electrical conductivity at 25° C. of at least 7 S/cm.

說(shuō)明書(shū)

Typically, the anode of a water electrolyser comprises a catalyst for the oxygen evolution reaction (an OER electrocatalyst). Appropriate OER electrocatalysts are known to the skilled person and have been described e.g. by M. Carmo et al., “A comprehensive review on PEM water electrolysis”, International Journal of Hydrogen Energy, Vol. 38, 2013, pp. 4901-4934; and H. Dau et al., “The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis”, ChemCatChem, 2010, 2, pp. 724-761.

S. P. Jiang and Y. Cheng, Progress in Natural Science: Materials International, 25 (2015), pp. 545-553, provide a review on electrocatalysts for the oxygen evolution reaction in water electrolysis.

It is known that iridium or ruthenium or oxides thereof are efficient catalysts for the oxygen evolution reaction. As iridium and ruthenium are expensive, it is desirable to have a sufficiently high catalytic activity even a low amounts of iridium and/or ruthenium, and a very low dissolution of these metals into the surrounding electrolyte under the highly corrosive operating conditions of PEM water electrolysers and fuel cells.

Bulk catalysts have a limited surface area for electrochemical activity. For increasing the catalytically active surface area, it is generally known to apply a catalyst on a support.

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