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Electrocatalyst composition comprising noble metal oxide supported on tin oxide

專利號(hào)
US11177483B2
公開(kāi)日期
2021-11-16
申請(qǐng)人
BASF SE(DE Ludwigshafen am Rhein)
發(fā)明人
Andreas Haas; Domnik Bayer; Rosalba Adriana Rincon-Ovalles; Markus Kohl
IPC分類
H01M4/90; H01M4/92; C25B11/093; C25B11/097
技術(shù)領(lǐng)域
iridium,tin,oxide,ruthenium,noble,bet,catalyst,m2,ato,sb
地域: Ludwigshafen am Rhein

摘要

The present invention relates to a catalyst composition, comprising tin oxide particles which are at least partially coated by a noble metal oxide layer, wherein the composition contains iridium and ruthenium in a total amount of from 10 wt % to 38 wt %, and all iridium and ruthenium is oxidized, —has a BET surface area of from 5 to 95 m2/g, and —has an electrical conductivity at 25° C. of at least 7 S/cm.

說(shuō)明書(shū)

V. K. Puthiyapura et al., Journal of Power Sources, 269 (2014), pp. 451-460, describe the preparation of an ATO-supported IrO2 catalyst via a so-called Adams fusion method, wherein H2IrCl6 and NaNO3 are added to an aqueous dispersion of antimony-doped tin oxide (ATO) particles. The solvent is evaporated and the obtained mixture is dried and calcined at 500° C. By this Adams fusion method, a composition of relatively low electrical conductivity is obtained, as shown by FIG. 6 of said publication. Emma Oakton et al., New J. Chem., 2016, 40, pp. 1834-1838, describe the preparation of a high surface area iridium oxide/titanium oxide composition via the Adams fusion method by dissolving a Ti salt, an Ir salt and NaNO3 in water, evoparating the water, drying the mixture, followed by calcination at 350° C. A composition of relatively low electrical conductivity is obtained, as shown by FIG. 4 of said publication.

EP 2 608 297 A1 describes a catalyst composition for water electrolysis, comprising iridium oxide and a high surface area inorganic oxide, having a BET surface area in the range of 30 to 200 m2/g, wherein the inorganic oxide is present in an amount of from 25 to 70 wt % based on the total weight of the catalyst and wherein the electrical conductivity of the catalyst is >0.01 S/cm.

The object of the present invention is to provide a composition which is an effective electrocatalyst, in particular for the oxygen evolution reaction, shows high stability under very corrosive conditions (e.g. in PEM water electrolysers or PEM fuel cells), and is viable from an economical point of view.

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