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Electrocatalyst composition comprising noble metal oxide supported on tin oxide

專利號(hào)
US11177483B2
公開(kāi)日期
2021-11-16
申請(qǐng)人
BASF SE(DE Ludwigshafen am Rhein)
發(fā)明人
Andreas Haas; Domnik Bayer; Rosalba Adriana Rincon-Ovalles; Markus Kohl
IPC分類
H01M4/90; H01M4/92; C25B11/093; C25B11/097
技術(shù)領(lǐng)域
iridium,tin,oxide,ruthenium,noble,bet,catalyst,m2,ato,sb
地域: Ludwigshafen am Rhein

摘要

The present invention relates to a catalyst composition, comprising tin oxide particles which are at least partially coated by a noble metal oxide layer, wherein the composition contains iridium and ruthenium in a total amount of from 10 wt % to 38 wt %, and all iridium and ruthenium is oxidized, —has a BET surface area of from 5 to 95 m2/g, and —has an electrical conductivity at 25° C. of at least 7 S/cm.

說(shuō)明書

The object is solved by a catalyst composition, comprising tin oxide particles, wherein the tin oxide is optionally doped with at least one metal dopant, the tin oxide particles being at least partially coated by a noble metal oxide layer, wherein the noble metal oxide is an iridium oxide or an iridium-ruthenium oxide, wherein the composition

    • contains iridium and ruthenium in a total amount of from 10 wt % to 38 wt %, and all iridium and ruthenium is oxidized,
    • has a BET surface area of from 5 to 95 m2/g, and
    • has an electrical conductivity at 25° C. of at least 7 S/cm.

BRIEF DESCRIPTION OF THE FIGURES

FIGS. 1a and 1b show scanning transmission electron microscopy photographs with EDXS mapping.

FIGS. 2a and 2b show scanning transmission electron microscopy photographs with EDXS mapping.

A composition which complies with these features shows a surprisingly high catalytic activity towards an oxygen evolution reaction, and is very stable under highly corrosive conditions. Furthermore, as the total amount of iridium and, if present, ruthenium is kept on a relatively low level, a very cost-efficient catalyst composition is obtained.

權(quán)利要求

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