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Electrocatalyst composition comprising noble metal oxide supported on tin oxide

專利號
US11177483B2
公開日期
2021-11-16
申請人
BASF SE(DE Ludwigshafen am Rhein)
發(fā)明人
Andreas Haas; Domnik Bayer; Rosalba Adriana Rincon-Ovalles; Markus Kohl
IPC分類
H01M4/90; H01M4/92; C25B11/093; C25B11/097
技術(shù)領(lǐng)域
iridium,tin,oxide,ruthenium,noble,bet,catalyst,m2,ato,sb
地域: Ludwigshafen am Rhein

摘要

The present invention relates to a catalyst composition, comprising tin oxide particles which are at least partially coated by a noble metal oxide layer, wherein the composition contains iridium and ruthenium in a total amount of from 10 wt % to 38 wt %, and all iridium and ruthenium is oxidized, —has a BET surface area of from 5 to 95 m2/g, and —has an electrical conductivity at 25° C. of at least 7 S/cm.

說明書

As will be discussed below in further detail, the noble metal oxide is applied onto the tin oxide particles via pH-initiated precipitation of noble metal species, followed by thermal treatment at high temperature. By this method, a catalyst composition is typically obtained which has a BET surface area being lower than the BET surface area of the non-coated tin oxide starting material. Accordingly, for providing a catalyst composition having a BET surface area of from 5 to 95 m2/g, a tin oxide (either doped or non-doped) having a slightly higher BET surface area is typically subjected to the noble metal oxide deposition treatment. The tin oxide starting material can have a BET surface area of e.g. from 10 m2/g to 100 m2/g.

As indicated above, each of the tin oxide particles is at least partially coated by a noble metal oxide layer, wherein the noble metal oxide is an iridium oxide or an iridium-ruthenium oxide.

The formation of a noble metal oxide layer on the tin oxide particles even at relatively low amounts of noble metal (instead of forming isolated oxide particles being distributed over the support surface) results from applying the preparation method as described below (i.e. pH-induced precipitation from an aqueous medium, followed by calcination at high temperature). The presence of a noble metal oxide coating layer on a tin oxide particle assists in improving electrical conductivity of the catalyst composition, which in turn improves electron transfer efficiency during the catalytic reaction. For obtaining an electrical conductivity of at least 7 S/cm, a noble metal oxide layer which is partially coating the carrier particle can be sufficient. However, in the present invention, it is also possible that the tin oxide particles are completely coated by the noble metal oxide layer.

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