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Redox flow battery

專利號
US11177497B2
公開日期
2021-11-16
申請人
Shrihari Sankarasubramanian; Vijay K. Ramani(US MO St. Louis)
發(fā)明人
Shrihari Sankarasubramanian; Vijay K. Ramani
IPC分類
H01M8/18; H01M8/1004; H01M8/04791; H01M8/083
技術(shù)領(lǐng)域
rfb,ce,ion,metal,acid,in,redox,ce4,membrane,ti
地域: MO MO St. Louis

摘要

Disclosed herein is a redox flow battery (RFB). The battery generally includes: a positive electrolyte that is a first metal ion, a negative electrolyte that is a second metal ion, an ion exchange membrane positioned between the positive electrolyte and the negative electrolyte. The membrane is configured to restrict and/or prevent the passage of the first metal ion and/or the second metal ion therethrough, and is configured to maintain ionic conductivity between the positive electrolyte and the negative electrolyte.

說明書

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FIG. 3 illustrates the projected installed system cost of an electrode-decoupled Ti—Ce redox flow battery at different productions scales for a 1 MWh module.

FIG. 4 is a schematic of one aspect of an electrode-decoupled titanium-cerium RFB.

FIG. 5 illustrates a polarization curve of an electrode-decoupled Ti—Ce RFB with a quaternized Cardo-poly(etherketone) membrane, 0.5 M TiOSO4/3 M H2SO4 negative electrolyte, 0.5 M Ce(SO4)2/3 M H2SO4 positive electrolyte at a flow rate of 100 mL/min.

FIG. 6A illustrates a representative charge-discharge curve of an electrode-decoupled Ti—Ce RFB with a quaternized Cardo-poly(etherketone) membrane, 0.5 M TiOSO4/3 M H2SO4 negative electrolyte, 0.5 M Ce(SO4)2/3 M H2SO4 positive electrolyte at a flow rate of 100 mL/min and a 0.5 A current. FIG. 6B illustrates the charge-discharge curve of an electrode-decoupled Ti—Ce RFB with a quaternized Cardo-poly(etherketone) membrane, 0.9 M TiOSO4/4 M CH3SO3H negative electrolyte, 0.9 M Ce(CH3SO3)3/4 M CH3SO3H positive electrolyte at a flow rate of 100 mL/min and a 0.5 A current.

權(quán)利要求

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