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Production method for non-aqueous electrolyte secondary battery active material providing lithium insertion and solution contact

專利號
US11177501B2
公開日期
2021-11-16
申請人
SHIN-ETSU CHEMICAL CO., LTD.(JP Tokyo)
發(fā)明人
Hiromichi Kamo; Takakazu Hirose
IPC分類
H01M10/0525; H01M4/13; H01M4/48; H01M4/139; H01M4/1391; H01M4/1395; H01M4/38; H01M4/485; H01M10/0569; H01M4/02; H01M10/0587
技術領域
electrode,compound,silicon,lithium,solution,negative,solvent,battery,active,in
地域: Tokyo

摘要

A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing a silicon compound (SiOx: 0.5≤x≤1.6) that contains Li, includes: making a silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof (here, the solution B contains one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent); and making the silicon compound contact with a solution C (here, the solution C contains one or more kinds selected from an alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent). Thereby, a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing a battery capacity and improving the cycle characteristics.

說明書

TECHNICAL FIELD

The present invention relates to a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries, a production method of a negative electrode for non-aqueous electrolyte secondary batteries, and a non-aqueous electrolyte secondary battery.

BACKGROUND ART

In recent years, small-sized electronic devices represented by mobile terminals and the like have been widely spread and further down-sizing, lighter weight and longer life are strongly demanded. To a market demand like this, secondary batteries capable of obtaining, in particular, a smaller size, a lighter weight and a higher energy density have been developed. The secondary batteries are studied to apply also to, without limiting to small-sized electronic devices, large-sized electronic devices represented by automobiles and power-storage systems represented by houses or the like.

Among these, a lithium ion secondary battery is highly expected because it may readily obtain a smaller size and higher capacity and may obtain the energy density higher than that of a lead battery or a nickel-cadmium battery.

A lithium ion secondary battery includes an electrolytic solution together with a positive electrode and a negative electrode, and a separator. The negative electrode includes a negative electrode active material involving a charge/discharge reaction.

權利要求

1
The invention claimed is:1. A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing SiOx wherein 0.5≤x≤1.6 as a silicon compound that contains Li, comprising the steps of:preparing SiOx wherein 0.5≤x≤1.6 as a silicon compound;forming a carbon film on a surface of the silicon compound;inserting lithium into the silicon compound covered with the carbon film with a solution A containing lithium, an ether-based solvent and a straight chain polyphenylene compound or its derivative;making the silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof containing one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent to thereby desorb only a part of the lithium from the silicon compound wherein lithium is inserted; andmaking the silicon compound that has been contacted with the solution B contact with a solution C containing one or more kinds selected from the alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent,wherein treatment conditions when contacting the silicon compound into which the lithium has been inserted with the solution B are adjusted to desorb only a part of the lithium, the treatment conditions including at least a concentration of the polycyclic aromatic compound or a derivative thereof or both thereof in the solution B; a reaction temperature when contacting the silicon compound into which the lithium has been inserted with the solution B; and a contact time of the silicon compound into which the lithium has been inserted with the solution B.2. The production method of a negative electrode active material for non-aqueous electrolyte secondary batteries according to claim 1, wherein in the step of making the silicon compound contact with the solution B, the silicon compound is contacted with the solution B for 3 minutes or longer.3. The production method of a negative electrode active material for non-aqueous electrolyte secondary batteries according to claim 1, wherein in the step of inserting lithium, the silicon compound is contacted with the solution A for 3 minutes or longer to insert the lithium into the silicon compound.4. The production method of a negative electrode active material for non-aqueous electrolyte secondary batteries according to claim 2, wherein in the step of inserting lithium, the silicon compound is contacted with the solution A for 3 minutes or longer to insert the lithium into the silicon compound.5. The production method of a negative electrode active material for non-aqueous electrolyte secondary batteries according to claim 1, wherein one or more kinds of biphenyl, terphenyl, and derivative thereof are used as the straight chain polyphenylene compound.6. The production method of a negative electrode active material for non-aqueous electrolyte secondary batteries according to claim 1, wherein one containing the alcohol-based solvent or water as the solvent is used as the solution C.7. The production method of a negative electrode active material for non-aqueous electrolyte secondary batteries according to claim 1, wherein the method includes the step of forming an electrode containing the silicon compound before the step of inserting lithium, and to the silicon compound contained in the electrode, the step of inserting lithium, the step of making the silicon compound contact with the solution B, and the step of making the silicon compound contact with the solution C are applied.8. A non-aqueous electrolyte secondary battery having an electrode containing the negative electrode active material for non-aqueous electrolyte secondary batteries produced according to the production method of negative electrode active material for non-aqueous electrolyte secondary batteries according to claim 1.
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