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Production method for non-aqueous electrolyte secondary battery active material providing lithium insertion and solution contact

專利號
US11177501B2
公開日期
2021-11-16
申請人
SHIN-ETSU CHEMICAL CO., LTD.(JP Tokyo)
發(fā)明人
Hiromichi Kamo; Takakazu Hirose
IPC分類
H01M10/0525; H01M4/13; H01M4/48; H01M4/139; H01M4/1391; H01M4/1395; H01M4/38; H01M4/485; H01M10/0569; H01M4/02; H01M10/0587
技術領域
electrode,compound,silicon,lithium,solution,negative,solvent,battery,active,in
地域: Tokyo

摘要

A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing a silicon compound (SiOx: 0.5≤x≤1.6) that contains Li, includes: making a silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof (here, the solution B contains one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent); and making the silicon compound contact with a solution C (here, the solution C contains one or more kinds selected from an alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent). Thereby, a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing a battery capacity and improving the cycle characteristics.

說明書

At this time, in the production method of the negative electrode active material of the present invention, as the solution A containing the lithium, a solution A1 containing lithium and a polycyclic aromatic compound or its derivative or a straight chain polyphenylene compound or its derivative, or a solution A2 containing lithium and an amine (here, the solution A1 and solution A2 contain the ether-based solvent as the solvent) may be used.

When the solvent like this is used as the solution A containing lithium, the Li may be more uniformly inserted in the silicon compound, in addition, the Li may be efficiently inserted.

Further, at this time, in the production method of the negative electrode active material of the present invention, as the solution A containing lithium, it is preferable to use the solution A1.

When the solution A1 is used, the Li may be particularly efficiently inserted. When the solution containing in particular the straight chain polyphenylene compound or its derivative is used as the solution A1, the Li may be inserted particularly efficiently.

權利要求

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