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Production method for non-aqueous electrolyte secondary battery active material providing lithium insertion and solution contact

專利號
US11177501B2
公開日期
2021-11-16
申請人
SHIN-ETSU CHEMICAL CO., LTD.(JP Tokyo)
發(fā)明人
Hiromichi Kamo; Takakazu Hirose
IPC分類
H01M10/0525; H01M4/13; H01M4/48; H01M4/139; H01M4/1391; H01M4/1395; H01M4/38; H01M4/485; H01M10/0569; H01M4/02; H01M10/0587
技術(shù)領(lǐng)域
electrode,compound,silicon,lithium,solution,negative,solvent,battery,active,in
地域: Tokyo

摘要

A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing a silicon compound (SiOx: 0.5≤x≤1.6) that contains Li, includes: making a silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof (here, the solution B contains one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent); and making the silicon compound contact with a solution C (here, the solution C contains one or more kinds selected from an alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent). Thereby, a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing a battery capacity and improving the cycle characteristics.

說明書

In the production method of the negative electrode active material of the present invention, after forming the silicon compound into the electrode, inserting lithium and contacting with the solution B and solution C may be performed. When the negative electrode active material is prepared like this, since the active Li portion contained in the silicon compound is deactivated in advance, even under low humidity environment, an excess Li compound is difficult to be generated on a surface of the active material, and the battery characteristics may be prevented from deteriorating.

Further, in order to achieve the above object, the present invention provides a non-aqueous electrolyte secondary battery having an electrode containing the negative electrode active material for non-aqueous electrolyte secondary batteries produced by the any one of the production methods of negative electrode active material for non-aqueous electrolyte secondary batteries.

By this configuration, since the battery characteristics may be suppressed from deteriorating due to heat generation during preparation of the electrode, generation of an excess Li compound on an electrode surface, or the like, non-aqueous electrolyte secondary batteries having excellent battery characteristics are formed.

權(quán)利要求

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