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Production method for non-aqueous electrolyte secondary battery active material providing lithium insertion and solution contact

專利號
US11177501B2
公開日期
2021-11-16
申請人
SHIN-ETSU CHEMICAL CO., LTD.(JP Tokyo)
發(fā)明人
Hiromichi Kamo; Takakazu Hirose
IPC分類
H01M10/0525; H01M4/13; H01M4/48; H01M4/139; H01M4/1391; H01M4/1395; H01M4/38; H01M4/485; H01M10/0569; H01M4/02; H01M10/0587
技術領域
electrode,compound,silicon,lithium,solution,negative,solvent,battery,active,in
地域: Tokyo

摘要

A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing a silicon compound (SiOx: 0.5≤x≤1.6) that contains Li, includes: making a silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof (here, the solution B contains one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent); and making the silicon compound contact with a solution C (here, the solution C contains one or more kinds selected from an alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent). Thereby, a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing a battery capacity and improving the cycle characteristics.

說明書

Further, like in the production method of the negative electrode of the present invention, the negative electrode may be prepared by carrying out inserting lithium, making contact with the solution B, and contacting with the solution C, after the electrode containing the prepared silicon compound is formed (step 5 of FIG. 1) after preparation of the silicon compound. More specifically, first, the electrode is formed, followed by inserting lithium in the silicon compound contained in the electrode. The lithium may be inserted, for example, by making contact the solution A with the electrode to make contact the solution A with the silicon compound in the electrode. Next, the electrode containing the silicon compound into which the lithium has been inserted is contacted with the solution B, thus, the silicon compound in the electrode is contacted with the solution B. Subsequently, by contacting the electrode that has been contacted with the solution B with the solution C, the silicon compound is contacted with the solution C. It is to be noted that, when the silicon compound in the electrode is contacted with the solutions A, B and C, the silicon compound contained in the electrode may be contacted with the solutions A, B and C, for example, by soaking the electrode in the solutions A, B and C, or by spraying the solutions A, B and C on the electrode.

(3. Lithium Ion Secondary Battery)

Next, a lithium ion secondary battery that uses the negative electrode for lithium ion secondary batteries will be described.

(Configuration of Laminate Film Type Secondary Battery)

權利要求

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