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Production method for non-aqueous electrolyte secondary battery active material providing lithium insertion and solution contact

專利號
US11177501B2
公開日期
2021-11-16
申請人
SHIN-ETSU CHEMICAL CO., LTD.(JP Tokyo)
發(fā)明人
Hiromichi Kamo; Takakazu Hirose
IPC分類
H01M10/0525; H01M4/13; H01M4/48; H01M4/139; H01M4/1391; H01M4/1395; H01M4/38; H01M4/485; H01M10/0569; H01M4/02; H01M10/0587
技術領域
electrode,compound,silicon,lithium,solution,negative,solvent,battery,active,in
地域: Tokyo

摘要

A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing a silicon compound (SiOx: 0.5≤x≤1.6) that contains Li, includes: making a silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof (here, the solution B contains one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent); and making the silicon compound contact with a solution C (here, the solution C contains one or more kinds selected from an alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent). Thereby, a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing a battery capacity and improving the cycle characteristics.

說明書

(Positive Electrode)

The positive electrode has, in the same manner as in the negative electrode 10 of, for example, FIG. 2, a positive electrode active material layer on both sides or on one side of a positive electrode current collector.

The positive electrode current collector is formed of a conductive material such as, for example, aluminum.

The positive electrode active material layer contains any one or more kinds of positive electrode materials capable of absorbing/releasing lithium ion, and, may contain other materials such as a binder, a conductive assistant, and a dispersant according to a design. In this case, details of the binder and the conductive assistant are the same as, for example, in the negative electrode binder and the negative electrode conductive assistant described above.

As the positive electrode material, a Li-containing compound is desirable. As the Li-containing compound, a composite oxide made of, for example, lithium and a transition metal element, or a phosphate compound having Li and the transition metal element may be used. Among these positive electrode materials, compounds containing at least one or more kinds of nickel, iron, manganese, and cobalt are preferred. Chemical formulas for these are represented by, for example, LixM1O2 or LiyM2PO4. In the formulas, M1 and M2 represent at least one or more kinds of the transition metal elements. Values of x and y show different values depending on a battery charge/discharge state, but, are generally shown by 0.5≤×≤1.10 and 0.05≤y≤1.10.

權利要求

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