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Pyridine sulfur trioxide complexes as electrolyte component for high voltage batteries

專利號(hào)
US11177505B2
公開日期
2021-11-16
申請(qǐng)人
BASF SE; University of Rhode Island Board of Trustees(DE Ludwigshafen am Rhein)
發(fā)明人
Frederick Francois Chesneau; Arnd Garsuch; Michael Schmidt; Brett Lucht; Julien Demeaux; Yingnan Dong; Bo Zhang
IPC分類
H01M10/0567; H01M10/0525; H01M10/0568; H01M10/0569
技術(shù)領(lǐng)域
so3,lithium,pyridine,c10,carbonate,alkyl,cyclic,or,selected,wt
地域: Ludwigshafen am Rhein

摘要

An electrolyte composition including (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one pyridine-SO3 complex of formula (I) wherein R is selected independently at each occurrence from F, C1 to C10 alkyl, C2 to C10 alkenyl, and C2 to C10 alkynyl, wherein alkyl, alkenyl, and alkynyl may be substituted by one or more substituents selected from F and CN; and n is an integer selected from 1, 2, 3, 4, and 5; and (vi) optionally one or more additives; and its use in electrochemical cells.

說明書

Examples of fluorinated ethers of formula R′—(O—CFpH2?p)q—R″ are 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (CF2HCF2CH2OCF2CF2H), and 1H,1H,5H-perfluoropentyl-1,1,2,2-tetrafluoroethylether (CF2H(CF2)3CH2OCF2CF2H).

Examples of optionally fluorinated cyclic ethers are 1,4-dioxane, tetrahydrofuran, and their derivatives like 2-methyl tetrahydrofuran wherein one or more H of an alkyl group may be substituted by F.

Examples of optionally fluorinated acyclic acetals are 1,1-dimethoxymethane and 1,1-diethoxymethane. Examples of cyclic acetals are 1,3-dioxane, 1,3-dioxolane, and their derivatives such as methyl dioxolane wherein one or more H may be substituted by F.

Examples of optionally fluorinated acyclic orthocarboxylic acid esters are tri-C1-C4 alkoxy methane, in particular trimethoxymethane and triethoxymethane. Examples of suitable cyclic orthocarboxylic acid esters are 1,4-dimethyl-3,5,8-trioxabicyclo[2.2.2]octane and 4-ethyl-1-methyl-3,5,8-trioxabicyclo[2.2.2]octane wherein one or more H may be substituted by F.

Examples of optionally fluorinated acyclic esters of carboxylic acids are ethyl and methyl formate, ethyl and methyl acetate, ethyl and methyl proprionate, and ethyl and methyl butanoate, and esters of dicarboxylic acids like 1,3-dimethyl propanedioate wherein one or more H may be substituted by F. An example of a cyclic ester of carboxylic acids (lactones) is γ-butyrolactone.

Examples of optionally fluorinated cyclic and acyclic sulfones are ethyl methyl sulfone, dimethyl sulfone, and tetrahydrothiophene-S,S-dioxide (sulfolane).

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