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Pyridine sulfur trioxide complexes as electrolyte component for high voltage batteries

專利號
US11177505B2
公開日期
2021-11-16
申請人
BASF SE; University of Rhode Island Board of Trustees(DE Ludwigshafen am Rhein)
發(fā)明人
Frederick Francois Chesneau; Arnd Garsuch; Michael Schmidt; Brett Lucht; Julien Demeaux; Yingnan Dong; Bo Zhang
IPC分類
H01M10/0567; H01M10/0525; H01M10/0568; H01M10/0569
技術領域
so3,lithium,pyridine,c10,carbonate,alkyl,cyclic,or,selected,wt
地域: Ludwigshafen am Rhein

摘要

An electrolyte composition including (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one pyridine-SO3 complex of formula (I) wherein R is selected independently at each occurrence from F, C1 to C10 alkyl, C2 to C10 alkenyl, and C2 to C10 alkynyl, wherein alkyl, alkenyl, and alkynyl may be substituted by one or more substituents selected from F and CN; and n is an integer selected from 1, 2, 3, 4, and 5; and (vi) optionally one or more additives; and its use in electrochemical cells.

說明書

According to another embodiment at least one R is OSi(OR1)3. R1 is selected independently at each occurrence from C1 to C10 alkyl, C2 to C10 alkenyl, and C2 to C10 alkynyl, wherein alkyl, alkenyl, and alkynyl may be substituted by one or more substituents selected from F and CN, preferably R1 is selected independently at each occurrence from C1 to C10 alkyl, which may be substituted by one or more substituents selected from F and CN, more preferred R1 is selected independently at each occurrence from C1 to C6 alkyl, which may be substituted by one or more substituents selected from F and CN, e.g. R1 is selected independently at each occurrence from methyl, ethyl, n-propyl, i-propyl, n-butyl, t-butyl, n-pentyl, i-pentyl, and n-hexyl. Examples of R selected from OSi(OR1)3 are trimethyl silyl and triethyl silyl.

n is an integer selected from 1, 2, 3, 4, and 5, preferably n is 1 or 2, more preferred n is 1.

Examples of pyridine-SO3 complexes of formula (I) are 2-vinyl pyridine sulfur trioxide, 3-vinyl pyridine sulfur trioxide, 4-vinyl pyridine sulfur trioxide, 2-trifluoromethyl pyridine sulfur trioxide, 3-trifluoromethyl pyridine sulfur trioxide, 4-trifluoromethyl pyridine sulfur trioxide, 2-fluoro pyridine sulfur trioxide, 3-fluoro pyridine sulfur trioxide, 4-fluoro pyridine sulfur trioxide, 2-propargyl pyridine sulfur trioxide, 3-propargyl pyridine sulfur trioxide, 4-propargyl pyridine sulfur trioxide, 2-trimethylsilyl pyridine sulfur trioxide, 3-trimethylsilyl pyridine sulfur trioxide, and 4-trimethylsilyl pyridine sulfur trioxide.

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