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Pyridine sulfur trioxide complexes as electrolyte component for high voltage batteries

專利號(hào)
US11177505B2
公開日期
2021-11-16
申請(qǐng)人
BASF SE; University of Rhode Island Board of Trustees(DE Ludwigshafen am Rhein)
發(fā)明人
Frederick Francois Chesneau; Arnd Garsuch; Michael Schmidt; Brett Lucht; Julien Demeaux; Yingnan Dong; Bo Zhang
IPC分類
H01M10/0567; H01M10/0525; H01M10/0568; H01M10/0569
技術(shù)領(lǐng)域
so3,lithium,pyridine,c10,carbonate,alkyl,cyclic,or,selected,wt
地域: Ludwigshafen am Rhein

摘要

An electrolyte composition including (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one pyridine-SO3 complex of formula (I) wherein R is selected independently at each occurrence from F, C1 to C10 alkyl, C2 to C10 alkenyl, and C2 to C10 alkynyl, wherein alkyl, alkenyl, and alkynyl may be substituted by one or more substituents selected from F and CN; and n is an integer selected from 1, 2, 3, 4, and 5; and (vi) optionally one or more additives; and its use in electrochemical cells.

說明書

The electrolyte composition contains at least one aprotic organic solvent (i). The aprotic organic solvent(s) (i) may be selected from optionally fluorinated aprotic organic solvents, i.e. from fluorinated and non-fluorinated aprotic organic solvents. The electrolyte composition may contain a mixture of fluorinated and non-fluorinated aprotic organic solvents.

The aprotic organic solvent is preferably selected from optionally fluorinated cyclic and acyclic organic carbonates, optionally fluorinated acyclic ethers and polyethers, optionally fluorinated cyclic ethers, optionally fluorinated cyclic and acyclic acetales and ketales, optionally fluorinated orthocarboxylic acids esters, optionally fluorinated cyclic and acyclic esters and diesters of carboxylic acids, optionally fluorinated cyclic and acyclic sulfones, optionally fluorinated cyclic and acyclic nitriles and dinitriles, and optionally fluorinated cyclic and acyclic phosphates, and mixtures thereof.

Examples of optionally fluorinated cyclic carbonates are ethylene carbonate (EC), propylene carbonate (PC) and butylene carbonate (BC), wherein one or more H may be substituted by F and/or an C1 to C4 alkyl group, e.g. 4-methyl ethylene carbonate, monofluoroethylene carbonate (FEC), and cis- and trans-difluoroethylene carbonate. Preferred optionally fluorinated cyclic carbonates are ethylene carbonate, monofluoroethylene carbonate, and propylene carbonate, in particular ethylene carbonate.

權(quán)利要求

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