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Electrolytes for a metal-ion battery cell with high-capacity, micron-scale, volume-changing anode particles

專(zhuān)利號(hào)
US11177509B2
公開(kāi)日期
2021-11-16
申請(qǐng)人
Sila Nanotechnologies, Inc.(US CA Alameda)
發(fā)明人
Gleb Yushin; Ashleigh Ward
IPC分類(lèi)
H01M10/0569; H01M4/525; H01M4/505; H01M10/0568; H01M10/0525; H01M4/38
技術(shù)領(lǐng)域
elr,vol,in,li,lmp,about,solvent,anode,fec,solvents
地域: CA CA Alameda

摘要

In an embodiment, a metal-ion battery cell comprises an anode electrode, a cathode electrode, a separator, and electrolyte ionically coupling the anode electrode and the cathode electrode. The anode electrode is a high-capacity electrode (e.g., in the range of about 2 mAh/cm2 to about 10 mAh/cm2) and the cathode electrode comprises an intercalation-type active material including at least Li, one or more metals, and oxygen. The electrolyte includes a solvent composition having low-melting point (LMP) solvent(s) in the range from about 10 vol. % to about 95 vol. % of the solvent composition.

說(shuō)明書(shū)

FIG. 1 illustrates an example metal-ion (e.g., Li-ion) battery in which the components, materials, methods, and other techniques described herein, or combinations thereof, may be applied according to various embodiments. A cylindrical battery is shown here for illustration purposes, but other types of arrangements, including prismatic or pouch (laminate-type) batteries, may also be used as desired. The example battery 100 includes a negative anode 102, a positive cathode 103, a separator 104 interposed between the anode 102 and the cathode 103, an electrolyte (shown implicitly) impregnating the separator 104, a battery case 105, and a sealing member 106 sealing the battery case 105.

Conventional electrolytes for Li- or Na-based batteries of this type are generally composed of a 0.8-1.2 M (1M±0.2 M) solution of a single Li or Na salt (such as LiPF6 for Li-ion batteries and NaPF6 or NaClO4 salts for Na-ion batteries) in a mixture of carbonate solvents with 1-2 wt. % of other organic additives. Common organic additives may include nitriles, esters, sulfones, sulfoxides, phosphorous-based solvents, silicon-based solvents, ethers, and others. Such additive solvents may be modified (e.g., sulfonated or fluorinated).

權(quán)利要求

1
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