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Ferroelectric device film stacks with texturing layer, and method of forming such

專利號(hào)
US11659714B1
公開日期
2023-05-23
申請(qǐng)人
Kepler Computing Inc.(US CA San Francisco)
發(fā)明人
Niloy Mukherjee; Ramamoorthy Ramesh; Sasikanth Manipatruni; James Clarkson; FNU Atiquzzaman; Gabriel Antonio Paulius Velarde; Jason Y. Wu
IPC分類
H01L27/11507; H01L27/11502; H01L49/02; H01L27/11597; H01L27/11592; H01L27/11587
技術(shù)領(lǐng)域
templating,lattice,layer,or,angstroms,in,structure,constant,fe,some
地域: CA CA San Francisco

摘要

Described are ferroelectric device film stacks which include a templating or texturing layer or material deposited below a ferroelectric layer, to enable a crystal lattice of the subsequently deposited ferroelectric layer to template off this templating layer and provide a large degree of preferential orientation despite the lack of epitaxial substrates.

說明書

In some embodiments, the ferroelectric material of ferroelectric layer 320 includes one or more of: Pb, La, Zr, Ti, Bi, Fe, Mg, N, Hf, or Zr. In some embodiments, the ferroelectric material of ferroelectric layer 320 includes one of: PbxLa1-xZr or TiO3; pseudo-cubic BiFeO3 with lattice constant of about 3.97 Angstroms; pseudo-cubic LaxBi1-xFeO3 with lattice constant of about 3.96 Angstroms; tetragonal BaTiO3 with lattice constant of about 4 Angstroms; Relaxor Ferroelectrics including lead magnesium niobite-lead titanate (PMN-PT); or Ferroelectric Hf0.5Zr0.5O2 (HZO).

In various embodiments, the thicknesses of each layer (e.g., t311, t312, t313, t230) is in a range of 5 nm to 30 nm. In various embodiments, the total height HCFe of ferroelectric device 300 is in a range of 30 nm to 180 nm. In some embodiments, the lateral thickness LCFe of ferroelectric device 300 is in a range of 5 nm to 200 nm. In some embodiments, the thicknesses of each layer can be in a range of approximately 1 nm to 100 nm. The total height HCFe of ferroelectric device 300 would thus be in a range of about 6 nm to 600 nm. In some embodiments, ferroelectric device 300 is formed on top of substrate 314. Substrate 314 can be any suitable substrate such as Si substrate, SiO2 substrate, metal substrate (e.g., W, Ag, Au, Co, Cu, Fe, Al, or a combination of them). In some embodiments, substrate 314 can have both oxide and metals exposed simultaneously, for example in the backend section of an integrated device flow, such that the ferroelectric layer is deposited on such a composite substrate.

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